Chemoenzymatic total synthesis of the phytotoxic geranylcyclohexentriol (-)-phomentrioloxin

Xinghua Ma; Martin G. Banwell; Anthony C. Willis

doi:10.1021/np4002866

Chemoenzymatic total synthesis of the phytotoxic geranylcyclohexentriol (-)-phomentrioloxin

Xinghua Ma
, Martin G. Banwell^*
, Anthony C. Willis

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

The enantiomeric form, 1R, of the structure (1S) assigned to the phytotoxic natural product phomentrioloxin has been synthesized in seven steps from the homochiral cis-1,2-dihydrocatechol 3. These studies reveal that the true structure of phomentrioloxin is represented by 1R and not by 1S.

Original language	English
Pages (from-to)	1514-1518
Number of pages	5
Journal	Journal of Natural Products
Volume	76
Issue number	8
DOIs	https://doi.org/10.1021/np4002866
Publication status	Published - 23 Aug 2013

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title = "Chemoenzymatic total synthesis of the phytotoxic geranylcyclohexentriol (-)-phomentrioloxin",

abstract = "The enantiomeric form, 1R, of the structure (1S) assigned to the phytotoxic natural product phomentrioloxin has been synthesized in seven steps from the homochiral cis-1,2-dihydrocatechol 3. These studies reveal that the true structure of phomentrioloxin is represented by 1R and not by 1S.",

author = "Xinghua Ma and Banwell, \{Martin G.\} and Willis, \{Anthony C.\}",

year = "2013",

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AU - Ma, Xinghua

AU - Banwell, Martin G.

AU - Willis, Anthony C.

PY - 2013/8/23

Y1 - 2013/8/23

N2 - The enantiomeric form, 1R, of the structure (1S) assigned to the phytotoxic natural product phomentrioloxin has been synthesized in seven steps from the homochiral cis-1,2-dihydrocatechol 3. These studies reveal that the true structure of phomentrioloxin is represented by 1R and not by 1S.

AB - The enantiomeric form, 1R, of the structure (1S) assigned to the phytotoxic natural product phomentrioloxin has been synthesized in seven steps from the homochiral cis-1,2-dihydrocatechol 3. These studies reveal that the true structure of phomentrioloxin is represented by 1R and not by 1S.

UR - https://www.scopus.com/pages/publications/84883179355

U2 - 10.1021/np4002866

DO - 10.1021/np4002866

M3 - Article

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SP - 1514

EP - 1518

JO - Journal of Natural Products

JF - Journal of Natural Products

IS - 8

ER -

Chemoenzymatic total synthesis of the phytotoxic geranylcyclohexentriol (-)-phomentrioloxin

Abstract

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