Abstract
A side-product that accompanies the synthesis of the widely utilized starting material TpRu(PPh3)2Cl (Tp = hydridotris(pyrazolyl)borate) has been identified as the complex clTpRu(PPh3)2H (clTp - chlorotris(pyrazolyl)bo-rate), which provides a rare example of a boron-halogenated pyrazolylborate ligand. The reaction of clTpRu(PPh3)2H with dichloromethane or chloroform quantitatively produce clTpRu(PPh3) 2Cl.
Original language | English |
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Pages (from-to) | 374-377 |
Number of pages | 4 |
Journal | Organometallics |
Volume | 28 |
Issue number | 1 |
DOIs | |
Publication status | Published - 12 Jan 2009 |