Chlorophosphino Carbyne Complexes of Tungsten

Annie L. Colebatch; Anthony F. Hill

doi:10.1021/acs.organomet.6b00314

Chlorophosphino Carbyne Complexes of Tungsten

Annie L. Colebatch
, Anthony F. Hill^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

A range of chlorophosphinocarbyne complexes [W(-CPClR)(CO)₂(Tp∗)] (R = Cl, Cy, Ph; Tp∗ = hydrotris(3,5-dimethylpyrazol-1-yl)borate) has been prepared by reaction of chlorophosphines with the lithiocarbyne complex [W{-CLi(THF)_n}(CO)₂(Tp∗)]. These complexes undergo nucleophilic substitution of chloride to enable the preparation of phosphinocarbynes bearing alkyl, aryl, alkynyl, aryloxy, and secondary phosphino substituents [W(-CPRR′)(CO)₂(Tp∗)] (R = Ph, R′ = Me, Ph, C-CPh, OPh, H; R = Cy, R′ = H).

Original language	English
Pages (from-to)	2249-2255
Number of pages	7
Journal	Organometallics
Volume	35
Issue number	13
DOIs	https://doi.org/10.1021/acs.organomet.6b00314
Publication status	Published - 11 Jul 2016

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title = "Chlorophosphino Carbyne Complexes of Tungsten",

abstract = "A range of chlorophosphinocarbyne complexes [W(-CPClR)(CO)2(Tp∗)] (R = Cl, Cy, Ph; Tp∗ = hydrotris(3,5-dimethylpyrazol-1-yl)borate) has been prepared by reaction of chlorophosphines with the lithiocarbyne complex [W\{-CLi(THF)n\}(CO)2(Tp∗)]. These complexes undergo nucleophilic substitution of chloride to enable the preparation of phosphinocarbynes bearing alkyl, aryl, alkynyl, aryloxy, and secondary phosphino substituents [W(-CPRR′)(CO)2(Tp∗)] (R = Ph, R′ = Me, Ph, C-CPh, OPh, H; R = Cy, R′ = H).",

author = "Colebatch, \{Annie L.\} and Hill, \{Anthony F.\}",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = jul,

day = "11",

doi = "10.1021/acs.organomet.6b00314",

language = "English",

volume = "35",

pages = "2249--2255",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "13",

}

TY - JOUR

T1 - Chlorophosphino Carbyne Complexes of Tungsten

AU - Colebatch, Annie L.

AU - Hill, Anthony F.

PY - 2016/7/11

Y1 - 2016/7/11

N2 - A range of chlorophosphinocarbyne complexes [W(-CPClR)(CO)2(Tp∗)] (R = Cl, Cy, Ph; Tp∗ = hydrotris(3,5-dimethylpyrazol-1-yl)borate) has been prepared by reaction of chlorophosphines with the lithiocarbyne complex [W{-CLi(THF)n}(CO)2(Tp∗)]. These complexes undergo nucleophilic substitution of chloride to enable the preparation of phosphinocarbynes bearing alkyl, aryl, alkynyl, aryloxy, and secondary phosphino substituents [W(-CPRR′)(CO)2(Tp∗)] (R = Ph, R′ = Me, Ph, C-CPh, OPh, H; R = Cy, R′ = H).

AB - A range of chlorophosphinocarbyne complexes [W(-CPClR)(CO)2(Tp∗)] (R = Cl, Cy, Ph; Tp∗ = hydrotris(3,5-dimethylpyrazol-1-yl)borate) has been prepared by reaction of chlorophosphines with the lithiocarbyne complex [W{-CLi(THF)n}(CO)2(Tp∗)]. These complexes undergo nucleophilic substitution of chloride to enable the preparation of phosphinocarbynes bearing alkyl, aryl, alkynyl, aryloxy, and secondary phosphino substituents [W(-CPRR′)(CO)2(Tp∗)] (R = Ph, R′ = Me, Ph, C-CPh, OPh, H; R = Cy, R′ = H).

UR - https://www.scopus.com/pages/publications/84978819000

U2 - 10.1021/acs.organomet.6b00314

DO - 10.1021/acs.organomet.6b00314

M3 - Article

SN - 0276-7333

VL - 35

SP - 2249

EP - 2255

JO - Organometallics

JF - Organometallics

IS - 13

ER -

Chlorophosphino Carbyne Complexes of Tungsten

Abstract

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