Cis,cis,cis-aquabis[bis(diphenylphosphino)methane-κ2P, P′]chlororuthenium(II) hexafluorophosphate methanol 1.73-solvate

Anthony C. Willis; Gulliver T. Dalton; Joseph P. Morrall; Marie P. Cifuentes; Mark G. Humphrey

doi:10.1107/S1600536804016253

Cis,cis,cis-aquabis[bis(diphenylphosphino)methane-κ²P, P′]chlororuthenium(II) hexafluorophosphate methanol 1.73-solvate

Anthony C. Willis
, Gulliver T. Dalton
, Joseph P. Morrall
, Marie P. Cifuentes
, Mark G. Humphrey^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The title compound, [RuCl(C₂₅H₂₂P₂) ₂(H₂O)]PF₆·1.73CH₄O, contains a pseudo-octahedral ruthenium complex cation with two bidentate diphosphine ligands and cis-disposed chloro and aqua ligands, together with a disordered hexafluorophosphate anion and disordered methanol solvent molecules. Identification as an aquaruthenium(II) complex rather than a hydroxoruthenium(III) complex was confirmed by cyclic voltammetry.

Original language	English
Pages (from-to)	m1122-m1123
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	8
DOIs	https://doi.org/10.1107/S1600536804016253
Publication status	Published - Aug 2004

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@article{2962cd90c349499287a73de0a0550e14,

title = "Cis,cis,cis-aquabis[bis(diphenylphosphino)methane-κ2P, P′]chlororuthenium(II) hexafluorophosphate methanol 1.73-solvate",

abstract = "The title compound, [RuCl(C25H22P2) 2(H2O)]PF6·1.73CH4O, contains a pseudo-octahedral ruthenium complex cation with two bidentate diphosphine ligands and cis-disposed chloro and aqua ligands, together with a disordered hexafluorophosphate anion and disordered methanol solvent molecules. Identification as an aquaruthenium(II) complex rather than a hydroxoruthenium(III) complex was confirmed by cyclic voltammetry.",

author = "Willis, \{Anthony C.\} and Dalton, \{Gulliver T.\} and Morrall, \{Joseph P.\} and Cifuentes, \{Marie P.\} and Humphrey, \{Mark G.\}",

year = "2004",

month = aug,

doi = "10.1107/S1600536804016253",

language = "English",

volume = "60",

pages = "m1122--m1123",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "8",

}

TY - JOUR

T1 - Cis,cis,cis-aquabis[bis(diphenylphosphino)methane-κ2P, P′]chlororuthenium(II) hexafluorophosphate methanol 1.73-solvate

AU - Willis, Anthony C.

AU - Dalton, Gulliver T.

AU - Morrall, Joseph P.

AU - Cifuentes, Marie P.

AU - Humphrey, Mark G.

PY - 2004/8

Y1 - 2004/8

N2 - The title compound, [RuCl(C25H22P2) 2(H2O)]PF6·1.73CH4O, contains a pseudo-octahedral ruthenium complex cation with two bidentate diphosphine ligands and cis-disposed chloro and aqua ligands, together with a disordered hexafluorophosphate anion and disordered methanol solvent molecules. Identification as an aquaruthenium(II) complex rather than a hydroxoruthenium(III) complex was confirmed by cyclic voltammetry.

AB - The title compound, [RuCl(C25H22P2) 2(H2O)]PF6·1.73CH4O, contains a pseudo-octahedral ruthenium complex cation with two bidentate diphosphine ligands and cis-disposed chloro and aqua ligands, together with a disordered hexafluorophosphate anion and disordered methanol solvent molecules. Identification as an aquaruthenium(II) complex rather than a hydroxoruthenium(III) complex was confirmed by cyclic voltammetry.

UR - https://www.scopus.com/pages/publications/18444394355

U2 - 10.1107/S1600536804016253

DO - 10.1107/S1600536804016253

M3 - Article

SN - 1600-5368

VL - 60

SP - m1122-m1123

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -

Cis,cis,cis-aquabis[bis(diphenylphosphino)methane-κ²P, P′]chlororuthenium(II) hexafluorophosphate methanol 1.73-solvate

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