TY - JOUR
T1 - Cluster chemistry. L. Trapping of arylnitrenes formed by cleavage of azoarenes in reactions with M3(CO)12 (M = Fe or Ru)
T2 - X-ray structure of Ru3(μ3-NPh)2(μ-dppm)(CO)7
AU - Bruce, Michael I.
AU - Humphrey, Mark G.
AU - Shawkataly, Omar Bin
AU - Snow, Michael R.
AU - Tiekink, Edward R.T.
PY - 1986/11/11
Y1 - 1986/11/11
N2 - Trinuclear products obtained from reactions between M3(CO)12 (M = Fe or Ru) and azobenzenes are shown to have the structure M3(μ3-NAr)2(CO)9, rather than the o-semidine formulation proposed earlier. ETC CO-substitution reactions are similar to those of Ru3(CO)12, with isocyanides occupying axial sites and tertiary phosphines and phosphites occupying equatorial sites on the Ru3(μ3-NPh)2(μ-dppm)(CO)7, in which the dppm ligand spans the non-bonded Ru ... Ru vector.
AB - Trinuclear products obtained from reactions between M3(CO)12 (M = Fe or Ru) and azobenzenes are shown to have the structure M3(μ3-NAr)2(CO)9, rather than the o-semidine formulation proposed earlier. ETC CO-substitution reactions are similar to those of Ru3(CO)12, with isocyanides occupying axial sites and tertiary phosphines and phosphites occupying equatorial sites on the Ru3(μ3-NPh)2(μ-dppm)(CO)7, in which the dppm ligand spans the non-bonded Ru ... Ru vector.
UR - http://www.scopus.com/inward/record.url?scp=0038881502&partnerID=8YFLogxK
U2 - 10.1016/0022-328X(86)80446-6
DO - 10.1016/0022-328X(86)80446-6
M3 - Article
AN - SCOPUS:0038881502
SN - 0022-328X
VL - 315
SP - C51-C55
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 2
ER -