Cluster chemistry. L. Trapping of arylnitrenes formed by cleavage of azoarenes in reactions with M3(CO)12 (M = Fe or Ru): X-ray structure of Ru3(μ3-NPh)2(μ-dppm)(CO)7

Michael I. Bruce; Mark G. Humphrey; Omar Bin Shawkataly; Michael R. Snow; Edward R.T. Tiekink

doi:10.1016/0022-328X(86)80446-6

Cluster chemistry. L. Trapping of arylnitrenes formed by cleavage of azoarenes in reactions with M₃(CO)₁₂ (M = Fe or Ru): X-ray structure of Ru₃(μ₃-NPh)₂(μ-dppm)(CO)₇

Michael I. Bruce^*, Mark G. Humphrey, Omar Bin Shawkataly, Michael R. Snow, Edward R.T. Tiekink

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Trinuclear products obtained from reactions between M₃(CO)₁₂ (M = Fe or Ru) and azobenzenes are shown to have the structure M₃(μ₃-NAr)₂(CO)₉, rather than the o-semidine formulation proposed earlier. ETC CO-substitution reactions are similar to those of Ru₃(CO)₁₂, with isocyanides occupying axial sites and tertiary phosphines and phosphites occupying equatorial sites on the Ru₃(μ₃-NPh)₂(μ-dppm)(CO)₇, in which the dppm ligand spans the non-bonded Ru ... Ru vector.

Original language	English
Pages (from-to)	C51-C55
Journal	Journal of Organometallic Chemistry
Volume	315
Issue number	2
DOIs	https://doi.org/10.1016/0022-328X(86)80446-6
Publication status	Published - 11 Nov 1986
Externally published	Yes

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10.1016/0022-328X(86)80446-6

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@article{90697070de764cfaaee19169ee632bca,

title = "Cluster chemistry. L. Trapping of arylnitrenes formed by cleavage of azoarenes in reactions with M3(CO)12 (M = Fe or Ru): X-ray structure of Ru3(μ3-NPh)2(μ-dppm)(CO)7",

abstract = "Trinuclear products obtained from reactions between M3(CO)12 (M = Fe or Ru) and azobenzenes are shown to have the structure M3(μ3-NAr)2(CO)9, rather than the o-semidine formulation proposed earlier. ETC CO-substitution reactions are similar to those of Ru3(CO)12, with isocyanides occupying axial sites and tertiary phosphines and phosphites occupying equatorial sites on the Ru3(μ3-NPh)2(μ-dppm)(CO)7, in which the dppm ligand spans the non-bonded Ru ... Ru vector.",

author = "Bruce, \{Michael I.\} and Humphrey, \{Mark G.\} and Shawkataly, \{Omar Bin\} and Snow, \{Michael R.\} and Tiekink, \{Edward R.T.\}",

year = "1986",

month = nov,

day = "11",

doi = "10.1016/0022-328X(86)80446-6",

language = "English",

volume = "315",

pages = "C51--C55",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "2",

}

Cluster chemistry. L. Trapping of arylnitrenes formed by cleavage of azoarenes in reactions with M₃(CO)₁₂ (M = Fe or Ru): X-ray structure of Ru₃(μ₃-NPh)₂(μ-dppm)(CO)₇. / Bruce, Michael I.; Humphrey, Mark G.; Shawkataly, Omar Bin et al.
In: Journal of Organometallic Chemistry, Vol. 315, No. 2, 11.11.1986, p. C51-C55.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Cluster chemistry. L. Trapping of arylnitrenes formed by cleavage of azoarenes in reactions with M3(CO)12 (M = Fe or Ru)

T2 - X-ray structure of Ru3(μ3-NPh)2(μ-dppm)(CO)7

AU - Bruce, Michael I.

AU - Humphrey, Mark G.

AU - Shawkataly, Omar Bin

AU - Snow, Michael R.

AU - Tiekink, Edward R.T.

PY - 1986/11/11

Y1 - 1986/11/11

N2 - Trinuclear products obtained from reactions between M3(CO)12 (M = Fe or Ru) and azobenzenes are shown to have the structure M3(μ3-NAr)2(CO)9, rather than the o-semidine formulation proposed earlier. ETC CO-substitution reactions are similar to those of Ru3(CO)12, with isocyanides occupying axial sites and tertiary phosphines and phosphites occupying equatorial sites on the Ru3(μ3-NPh)2(μ-dppm)(CO)7, in which the dppm ligand spans the non-bonded Ru ... Ru vector.

AB - Trinuclear products obtained from reactions between M3(CO)12 (M = Fe or Ru) and azobenzenes are shown to have the structure M3(μ3-NAr)2(CO)9, rather than the o-semidine formulation proposed earlier. ETC CO-substitution reactions are similar to those of Ru3(CO)12, with isocyanides occupying axial sites and tertiary phosphines and phosphites occupying equatorial sites on the Ru3(μ3-NPh)2(μ-dppm)(CO)7, in which the dppm ligand spans the non-bonded Ru ... Ru vector.

UR - https://www.scopus.com/pages/publications/0038881502

U2 - 10.1016/0022-328X(86)80446-6

DO - 10.1016/0022-328X(86)80446-6

M3 - Article

AN - SCOPUS:0038881502

SN - 0022-328X

VL - 315

SP - C51-C55

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Cluster chemistry. L. Trapping of arylnitrenes formed by cleavage of azoarenes in reactions with M₃(CO)₁₂ (M = Fe or Ru): X-ray structure of Ru₃(μ₃-NPh)₂(μ-dppm)(CO)₇

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