Co-ordinative activation of phosphaalkynes: Methyl neopentylidene phosphorane complexes of ruthenium(II); crystal structure of [Ru(MeP=CHBut)Cl(I)(CO)(PPh3)2]

Robin B. Bedford; Anthony F. Hill; Cameron Jones; Andrew J.P. White; James D.E.T. Wilton-Ely

doi:10.1039/a607016g

Co-ordinative activation of phosphaalkynes: Methyl neopentylidene phosphorane complexes of ruthenium(II); crystal structure of [Ru(MeP=CHBu^t)Cl(I)(CO)(PPh₃)₂]

Robin B. Bedford, Anthony F. Hill^*, Cameron Jones, Andrew J.P. White, James D.E.T. Wilton-Ely

^*Corresponding author for this work

Research output: Contribution to journal › Comment/debate › peer-review

30 Citations (Scopus)

Abstract

The reactions of [Ru(P=CHBu^t)Cl(CA)(PPh₃)₂] (A = O or S) with iodomethane provided the phosphaalkene complexes [Ru(PMe=CHBu^t)Cl(I)(CA)(PPh₃)₂] (I trans to phosphaalkene), with one example (A = O) having been crystallographically characterised.

Original language	English
Pages (from-to)	139-140
Number of pages	2
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	2
DOIs	https://doi.org/10.1039/a607016g
Publication status	Published - 21 Jan 1997
Externally published	Yes

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title = "Co-ordinative activation of phosphaalkynes: Methyl neopentylidene phosphorane complexes of ruthenium(II); crystal structure of [Ru(MeP=CHBut)Cl(I)(CO)(PPh3)2]",

abstract = "The reactions of [Ru(P=CHBut)Cl(CA)(PPh3)2] (A = O or S) with iodomethane provided the phosphaalkene complexes [Ru(PMe=CHBut)Cl(I)(CA)(PPh3)2] (I trans to phosphaalkene), with one example (A = O) having been crystallographically characterised.",

author = "Bedford, {Robin B.} and Hill, {Anthony F.} and Cameron Jones and White, {Andrew J.P.} and Wilton-Ely, {James D.E.T.}",

year = "1997",

month = jan,

day = "21",

doi = "10.1039/a607016g",

language = "English",

pages = "139--140",

journal = "Journal of the Chemical Society - Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "2",

}

Co-ordinative activation of phosphaalkynes: Methyl neopentylidene phosphorane complexes of ruthenium(II); crystal structure of [Ru(MeP=CHBu^t)Cl(I)(CO)(PPh₃)₂]. / Bedford, Robin B.; Hill, Anthony F.; Jones, Cameron et al.
In: Journal of the Chemical Society - Dalton Transactions, No. 2, 21.01.1997, p. 139-140.

Research output: Contribution to journal › Comment/debate › peer-review

TY - JOUR

T1 - Co-ordinative activation of phosphaalkynes

T2 - Methyl neopentylidene phosphorane complexes of ruthenium(II); crystal structure of [Ru(MeP=CHBut)Cl(I)(CO)(PPh3)2]

AU - Bedford, Robin B.

AU - Hill, Anthony F.

AU - Jones, Cameron

AU - White, Andrew J.P.

AU - Wilton-Ely, James D.E.T.

PY - 1997/1/21

Y1 - 1997/1/21

N2 - The reactions of [Ru(P=CHBut)Cl(CA)(PPh3)2] (A = O or S) with iodomethane provided the phosphaalkene complexes [Ru(PMe=CHBut)Cl(I)(CA)(PPh3)2] (I trans to phosphaalkene), with one example (A = O) having been crystallographically characterised.

AB - The reactions of [Ru(P=CHBut)Cl(CA)(PPh3)2] (A = O or S) with iodomethane provided the phosphaalkene complexes [Ru(PMe=CHBut)Cl(I)(CA)(PPh3)2] (I trans to phosphaalkene), with one example (A = O) having been crystallographically characterised.

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U2 - 10.1039/a607016g

DO - 10.1039/a607016g

M3 - Comment/debate

AN - SCOPUS:33748612970

SN - 0300-9246

SP - 139

EP - 140

JO - Journal of the Chemical Society - Dalton Transactions

JF - Journal of the Chemical Society - Dalton Transactions

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ER -

Co-ordinative activation of phosphaalkynes: Methyl neopentylidene phosphorane complexes of ruthenium(II); crystal structure of [Ru(MeP=CHBu^t)Cl(I)(CO)(PPh₃)₂]

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