Comments on the entropy of nonequilibrium steady states

Denis J. Evans*, Lamberto Rondoni

*Corresponding author for this work

    Research output: Contribution to journalReview articlepeer-review

    34 Citations (Scopus)

    Abstract

    We discuss the entropy of nonequilibrium steady states. We analyze the so-called spontaneous production of entropy in certain reversible deterministic nonequilibrium system, and its link with the collapse of such systems towards an attractor that is of lower dimension than the dimension of phase space. This means that in the steady state limit, the Gibbs entropy diverges to negative infinity. We argue that if the Gibbs entropy is expanded in a series involving 1, 2,... body terms, the divergence of the Gibbs entropy is manifest only in terms involving integrals whose dimension is higher than, approximately, the Kaplan-Yorke dimension of the steady state attractor. All the low order terms are finite and sum in the weak field limit to the local equilibrium entropy of linear irreversible thermodynamics.

    Original languageEnglish
    Pages (from-to)895-920
    Number of pages26
    JournalJournal of Statistical Physics
    Volume109
    Issue number3-4
    DOIs
    Publication statusPublished - 2002

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