Complete metal-mediated reduction of the triple bond of a phosphaalkyne: X-ray structure of [Ru(PHFCH(2)Bu(t))Cl(Co)(CNC(6)H(3)Me(2)-2,6)(PPh(3))(2)]BF4 center dot CH2Cl2

Robin B. Bedford; David E. Hibbs; Anthony F. Hill; Michael B. Hursthouse; K. M. Abdul Malik; Cameron Jones

doi:10.1039/cc9960001895

Complete metal-mediated reduction of the triple bond of a phosphaalkyne: X-ray structure of [Ru(PHFCH(2)Bu(t))Cl(Co)(CNC(6)H(3)Me(2)-2,6)(PPh(3))(2)]BF4 center dot CH2Cl2

Robin B. Bedford
, David E. Hibbs
, Anthony F. Hill
, Michael B. Hursthouse
, K. M. Abdul Malik
, Cameron Jones

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

The reaction of [Ru(P=CHBu(t))Cl(CO)(CNC(6)H(3)Me(2)-2,6)(PPh(3))(2)] with HBF4 provides, rapidly and reversibly, the phosphaalkene complex [Ru(HP=CHBu(t))Cl(CO)(CNC(6)H(3)Me(2)-2,6)(PPh(3))(2)](+) which is converted by K[HF2] or [NBu(n)4]F to the structurally characterised fluorophosphine complex [Ru(PHFCH(2)Bu(t))Cl(CO)(CNC(6)H(3)Me(2)-2,6)(PPh(3))(2)](+).

Original language	English
Pages (from-to)	1895-1896
Number of pages	2
Journal	Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/cc9960001895
Publication status	Published - 21 Aug 1996
Externally published	Yes

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@article{c7aefcd85f264e24b63bfdb24989fc08,

title = "Complete metal-mediated reduction of the triple bond of a phosphaalkyne: X-ray structure of [Ru(PHFCH(2)Bu(t))Cl(Co)(CNC(6)H(3)Me(2)-2,6)(PPh(3))(2)]BF4 center dot CH2Cl2",

abstract = "The reaction of [Ru(P=CHBu(t))Cl(CO)(CNC(6)H(3)Me(2)-2,6)(PPh(3))(2)] with HBF4 provides, rapidly and reversibly, the phosphaalkene complex [Ru(HP=CHBu(t))Cl(CO)(CNC(6)H(3)Me(2)-2,6)(PPh(3))(2)](+) which is converted by K[HF2] or [NBu(n)4]F to the structurally characterised fluorophosphine complex [Ru(PHFCH(2)Bu(t))Cl(CO)(CNC(6)H(3)Me(2)-2,6)(PPh(3))(2)](+).",

author = "Bedford, \{Robin B.\} and Hibbs, \{David E.\} and Hill, \{Anthony F.\} and Hursthouse, \{Michael B.\} and Malik, \{K. M. Abdul\} and Cameron Jones",

year = "1996",

month = aug,

day = "21",

doi = "10.1039/cc9960001895",

language = "English",

pages = "1895--1896",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "16",

}

TY - JOUR

T1 - Complete metal-mediated reduction of the triple bond of a phosphaalkyne

T2 - X-ray structure of [Ru(PHFCH(2)Bu(t))Cl(Co)(CNC(6)H(3)Me(2)-2,6)(PPh(3))(2)]BF4 center dot CH2Cl2

AU - Bedford, Robin B.

AU - Hibbs, David E.

AU - Hill, Anthony F.

AU - Hursthouse, Michael B.

AU - Malik, K. M. Abdul

AU - Jones, Cameron

PY - 1996/8/21

Y1 - 1996/8/21

N2 - The reaction of [Ru(P=CHBu(t))Cl(CO)(CNC(6)H(3)Me(2)-2,6)(PPh(3))(2)] with HBF4 provides, rapidly and reversibly, the phosphaalkene complex [Ru(HP=CHBu(t))Cl(CO)(CNC(6)H(3)Me(2)-2,6)(PPh(3))(2)](+) which is converted by K[HF2] or [NBu(n)4]F to the structurally characterised fluorophosphine complex [Ru(PHFCH(2)Bu(t))Cl(CO)(CNC(6)H(3)Me(2)-2,6)(PPh(3))(2)](+).

AB - The reaction of [Ru(P=CHBu(t))Cl(CO)(CNC(6)H(3)Me(2)-2,6)(PPh(3))(2)] with HBF4 provides, rapidly and reversibly, the phosphaalkene complex [Ru(HP=CHBu(t))Cl(CO)(CNC(6)H(3)Me(2)-2,6)(PPh(3))(2)](+) which is converted by K[HF2] or [NBu(n)4]F to the structurally characterised fluorophosphine complex [Ru(PHFCH(2)Bu(t))Cl(CO)(CNC(6)H(3)Me(2)-2,6)(PPh(3))(2)](+).

UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:A1996VD29800020&DestLinkType=FullRecord&DestApp=WOS_CPL

U2 - 10.1039/cc9960001895

DO - 10.1039/cc9960001895

M3 - Article

SN - 1359-7345

SP - 1895

EP - 1896

JO - Chemical Communications

JF - Chemical Communications

IS - 16

ER -

Complete metal-mediated reduction of the triple bond of a phosphaalkyne: X-ray structure of [Ru(PHFCH(2)Bu(t))Cl(Co)(CNC(6)H(3)Me(2)-2,6)(PPh(3))(2)]BF4 center dot CH2Cl2

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