Construction of an iminoketenylidene

Liam K. Burt; Anthony F. Hill

doi:10.1039/d1cc03310g

Construction of an iminoketenylidene

Liam K. Burt, Anthony F. Hill^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The new isonitrile-μ-carbido complexes [WPt(μ-C)Br(CNR)(PPh3)(CO)2(Tp∗)] (R = C6H2Me3-2,4,6, C6H3Me2-2,6; Tp∗ = hydrotris(dimethylpyrazolyl)borate) rearrange irreversibly in polar solvents to provide the first examples of iminoketenylidene (CCNR) complexes.

Original language	English
Pages (from-to)	8480-8483
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	68
DOIs	https://doi.org/10.1039/d1cc03310g
Publication status	Published - 4 Sept 2021

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title = "Construction of an iminoketenylidene",

abstract = "The new isonitrile-μ-carbido complexes [WPt(μ-C)Br(CNR)(PPh3)(CO)2(Tp∗)] (R = C6H2Me3-2,4,6, C6H3Me2-2,6; Tp∗ = hydrotris(dimethylpyrazolyl)borate) rearrange irreversibly in polar solvents to provide the first examples of iminoketenylidene (CCNR) complexes.",

author = "Burt, {Liam K.} and Hill, {Anthony F.}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2021",

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doi = "10.1039/d1cc03310g",

language = "English",

volume = "57",

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journal = "Chemical Communications",

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AU - Burt, Liam K.

AU - Hill, Anthony F.

PY - 2021/9/4

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N2 - The new isonitrile-μ-carbido complexes [WPt(μ-C)Br(CNR)(PPh3)(CO)2(Tp∗)] (R = C6H2Me3-2,4,6, C6H3Me2-2,6; Tp∗ = hydrotris(dimethylpyrazolyl)borate) rearrange irreversibly in polar solvents to provide the first examples of iminoketenylidene (CCNR) complexes.

AB - The new isonitrile-μ-carbido complexes [WPt(μ-C)Br(CNR)(PPh3)(CO)2(Tp∗)] (R = C6H2Me3-2,4,6, C6H3Me2-2,6; Tp∗ = hydrotris(dimethylpyrazolyl)borate) rearrange irreversibly in polar solvents to provide the first examples of iminoketenylidene (CCNR) complexes.

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U2 - 10.1039/d1cc03310g

DO - 10.1039/d1cc03310g

M3 - Article

SN - 1359-7345

VL - 57

SP - 8480

EP - 8483

JO - Chemical Communications

JF - Chemical Communications

IS - 68

ER -

Construction of an iminoketenylidene

Abstract

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