Construction of an iminoketenylidene

Liam K. Burt, Anthony F. Hill*

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    4 Citations (Scopus)

    Abstract

    The new isonitrile-μ-carbido complexes [WPt(μ-C)Br(CNR)(PPh3)(CO)2(Tp∗)] (R = C6H2Me3-2,4,6, C6H3Me2-2,6; Tp∗ = hydrotris(dimethylpyrazolyl)borate) rearrange irreversibly in polar solvents to provide the first examples of iminoketenylidene (CCNR) complexes.

    Original languageEnglish
    Pages (from-to)8480-8483
    Number of pages4
    JournalChemical Communications
    Volume57
    Issue number68
    DOIs
    Publication statusPublished - 4 Sept 2021

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