Cooperative enhancement of optical nonlinearities in a porphyrin derivative bearing a pyrimidine chromophore at the periphery

Aijian Wang; Lingliang Long; Suci Meng; Xiufen Li; Wei Zhao; Yinglin Song; Marie P. Cifuentes; Mark G. Humphrey; Chi Zhang

doi:10.1039/c3ob40323h

Cooperative enhancement of optical nonlinearities in a porphyrin derivative bearing a pyrimidine chromophore at the periphery

Aijian Wang, Lingliang Long, Suci Meng, Xiufen Li, Wei Zhao, Yinglin Song, Marie P. Cifuentes, Mark G. Humphrey, Chi Zhang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

A novel porphyrin derivative bearing one D-π-A-π-D pyrimidine chromophore at the periphery was designed, prepared, and studied using the Z-scan technique, the results showing that this compound exhibits enhanced nonlinear optical (NLO) absorption, refraction and optical limiting responses. The significant NLO properties can be ascribed to an effective combination of distinct nonlinear mechanisms.

Original language	English
Pages (from-to)	4250-4257
Number of pages	8
Journal	Organic and Biomolecular Chemistry
Volume	11
Issue number	25
DOIs	https://doi.org/10.1039/c3ob40323h
Publication status	Published - 7 Jul 2013

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abstract = "A novel porphyrin derivative bearing one D-π-A-π-D pyrimidine chromophore at the periphery was designed, prepared, and studied using the Z-scan technique, the results showing that this compound exhibits enhanced nonlinear optical (NLO) absorption, refraction and optical limiting responses. The significant NLO properties can be ascribed to an effective combination of distinct nonlinear mechanisms.",

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AU - Wang, Aijian

AU - Long, Lingliang

AU - Meng, Suci

AU - Li, Xiufen

AU - Zhao, Wei

AU - Song, Yinglin

AU - Cifuentes, Marie P.

AU - Humphrey, Mark G.

AU - Zhang, Chi

PY - 2013/7/7

Y1 - 2013/7/7

N2 - A novel porphyrin derivative bearing one D-π-A-π-D pyrimidine chromophore at the periphery was designed, prepared, and studied using the Z-scan technique, the results showing that this compound exhibits enhanced nonlinear optical (NLO) absorption, refraction and optical limiting responses. The significant NLO properties can be ascribed to an effective combination of distinct nonlinear mechanisms.

AB - A novel porphyrin derivative bearing one D-π-A-π-D pyrimidine chromophore at the periphery was designed, prepared, and studied using the Z-scan technique, the results showing that this compound exhibits enhanced nonlinear optical (NLO) absorption, refraction and optical limiting responses. The significant NLO properties can be ascribed to an effective combination of distinct nonlinear mechanisms.

UR - https://www.scopus.com/pages/publications/84878789734

U2 - 10.1039/c3ob40323h

DO - 10.1039/c3ob40323h

M3 - Article

SN - 1477-0520

VL - 11

SP - 4250

EP - 4257

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 25

ER -

Cooperative enhancement of optical nonlinearities in a porphyrin derivative bearing a pyrimidine chromophore at the periphery

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