TY - JOUR
T1 - Coordinative activation of nitrosoarenes
T2 - synthesis and protonation of the osmaoxaziridine [OsCl(NO)(ONC6H5)PPh3)2]
AU - Herberhold, Max
AU - Hill, Anthony F.
PY - 1989/3/21
Y1 - 1989/3/21
N2 - Nitrosobenzene, reacts readily with [OsCl(NO)(PPh3)2(L)] (L = C2H4, PPh3) to replace the labile ligand, L, and form of complex [OsCl(NO)(ONPh)(PPh3)2] in which the nitrosoarene ligand is coordinated through both nitrogen and oxygen. The nitrosobenzene complex reacts reversibly with hydrogen chloride to provide a 1 1 adduct, formulated as the divalent osmium hydroxylamino complex [OsCl2{N-OH)Ph}(NO)(PPh3)2].
AB - Nitrosobenzene, reacts readily with [OsCl(NO)(PPh3)2(L)] (L = C2H4, PPh3) to replace the labile ligand, L, and form of complex [OsCl(NO)(ONPh)(PPh3)2] in which the nitrosoarene ligand is coordinated through both nitrogen and oxygen. The nitrosobenzene complex reacts reversibly with hydrogen chloride to provide a 1 1 adduct, formulated as the divalent osmium hydroxylamino complex [OsCl2{N-OH)Ph}(NO)(PPh3)2].
UR - http://www.scopus.com/inward/record.url?scp=0346239131&partnerID=8YFLogxK
U2 - 10.1016/0022-328X(89)87123-2
DO - 10.1016/0022-328X(89)87123-2
M3 - Article
AN - SCOPUS:0346239131
SN - 0022-328X
VL - 363
SP - 371
EP - 376
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 3
ER -