TY - JOUR
T1 - Coordinative Activation of Nitrosoarenes - Synthesis and Protonation of the Osmaoxaziridine [OsCl(NO)(ONC6H5)PPh3)2]
AU - Herberhold, Max
AU - Hill, Anthony F.
PY - 1989/3/21
Y1 - 1989/3/21
N2 - Nitrosobenzene, reacts readily with [OsCl(NO)(PPh3)2(L)] (L = C2H4, PPh3) to replace the labile ligand, L, and form of complex [OsCl(NO)(ONPh)(PPh3)2] in which the nitrosoarene ligand is coordinated through both nitrogen and oxygen. The nitrosobenzene complex reacts reversibly with hydrogen chloride to provide a 1 1 adduct, formulated as the divalent osmium hydroxylamino complex [OsCl2{N-OH)Ph}(NO)(PPh3)2].
AB - Nitrosobenzene, reacts readily with [OsCl(NO)(PPh3)2(L)] (L = C2H4, PPh3) to replace the labile ligand, L, and form of complex [OsCl(NO)(ONPh)(PPh3)2] in which the nitrosoarene ligand is coordinated through both nitrogen and oxygen. The nitrosobenzene complex reacts reversibly with hydrogen chloride to provide a 1 1 adduct, formulated as the divalent osmium hydroxylamino complex [OsCl2{N-OH)Ph}(NO)(PPh3)2].
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UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:A1989T930300012&DestLinkType=FullRecord&DestApp=WOS_CPL
U2 - 10.1016/0022-328X(89)87123-2
DO - 10.1016/0022-328X(89)87123-2
M3 - Article
AN - SCOPUS:0346239131
SN - 0022-328X
VL - 363
SP - 371
EP - 376
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 3
ER -