Copper-induced N–N bond cleavage results in an octanuclear expanded-core grid-like complex

Nicholas G. White; Jonathan A. Kitchen; John A. Joule; Sally Brooker

doi:10.1039/c2cc32018e

Copper-induced N–N bond cleavage results in an octanuclear expanded-core grid-like complex

Nicholas G. White, Jonathan A. Kitchen, John A. Joule, Sally Brooker^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Reaction of copper(I) acetate and 4-amino-3,5-di(2-pyridyl)-1,2,4-triazole (adpt) in methanol under ambient conditions yields octanuclear [Cu^II₈(dpt)₄(OH)₄(OAc)₈]; OAc = acetate anion, and dpt- = anion of deaminated adpt, 3,5-di(2-pyridyl)-1,2,4-triazolate. However, reaction of copper(II) acetate with dptH gives tetranuclear [Cu^II₄(dpt)₂(OH)(OMe)(OAc)₄].

Original language	English
Pages (from-to)	6229-6231
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	50
DOIs	https://doi.org/10.1039/c2cc32018e
Publication status	Published - 28 May 2012
Externally published	Yes

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@article{5ac9b2581a554b2795a62e657d713094,

title = "Copper-induced N–N bond cleavage results in an octanuclear expanded-core grid-like complex",

abstract = "Reaction of copper(I) acetate and 4-amino-3,5-di(2-pyridyl)-1,2,4-triazole (adpt) in methanol under ambient conditions yields octanuclear [CuII8(dpt)4(OH)4(OAc)8]; OAc = acetate anion, and dpt- = anion of deaminated adpt, 3,5-di(2-pyridyl)-1,2,4-triazolate. However, reaction of copper(II) acetate with dptH gives tetranuclear [CuII4(dpt)2(OH)(OMe)(OAc)4].",

author = "White, \{Nicholas G.\} and Kitchen, \{Jonathan A.\} and Joule, \{John A.\} and Sally Brooker",

year = "2012",

month = may,

day = "28",

doi = "10.1039/c2cc32018e",

language = "English",

volume = "48",

pages = "6229--6231",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "50",

}

TY - JOUR

T1 - Copper-induced N–N bond cleavage results in an octanuclear expanded-core grid-like complex

AU - White, Nicholas G.

AU - Kitchen, Jonathan A.

AU - Joule, John A.

AU - Brooker, Sally

PY - 2012/5/28

Y1 - 2012/5/28

N2 - Reaction of copper(I) acetate and 4-amino-3,5-di(2-pyridyl)-1,2,4-triazole (adpt) in methanol under ambient conditions yields octanuclear [CuII8(dpt)4(OH)4(OAc)8]; OAc = acetate anion, and dpt- = anion of deaminated adpt, 3,5-di(2-pyridyl)-1,2,4-triazolate. However, reaction of copper(II) acetate with dptH gives tetranuclear [CuII4(dpt)2(OH)(OMe)(OAc)4].

AB - Reaction of copper(I) acetate and 4-amino-3,5-di(2-pyridyl)-1,2,4-triazole (adpt) in methanol under ambient conditions yields octanuclear [CuII8(dpt)4(OH)4(OAc)8]; OAc = acetate anion, and dpt- = anion of deaminated adpt, 3,5-di(2-pyridyl)-1,2,4-triazolate. However, reaction of copper(II) acetate with dptH gives tetranuclear [CuII4(dpt)2(OH)(OMe)(OAc)4].

UR - https://www.scopus.com/pages/publications/84861651628

U2 - 10.1039/c2cc32018e

DO - 10.1039/c2cc32018e

M3 - Article

SN - 1359-7345

VL - 48

SP - 6229

EP - 6231

JO - Chemical Communications

JF - Chemical Communications

IS - 50

ER -

Copper-induced N–N bond cleavage results in an octanuclear expanded-core grid-like complex

Abstract

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