TY - JOUR
T1 - Copper(I) complex [Cu(ca2dapte)(NCS)] with the flexible N 2S2 Schiff-base tridentate ligand
T2 - Synthesis, characterization and crystal structure
AU - Morshedi, Mahbod
AU - Amirnasr, Mehdi
AU - Triki, Smail
AU - Khalaji, Aliakbar Dehno
PY - 2011/1
Y1 - 2011/1
N2 - New copper(I) complex involving the flexible N2S2 Schiff-base ligand ca2dapte [Cu(ca2dapte)(NCS)], [ca 2dapte = N,N'-bis-(cinnamaldehyde)-1,2-di(o-iminophenylthio) ethane], has been synthesized and structurally characterized by X-ray diffraction analysis. The coordination polyhedron around the Cu(I) center is best described as a distorted tetrahedron. The flexible N2S2 Schiff-base ligand ca2dapte acts as a tridentate ligand via two S atoms and one N atom, while the NCS- ligand is coordinated to the metal ion through its nitrogen atom. Crystal data: space group P-1, a = 10.7486(7), b = 12.3737(13), c = 12.7578(11) Å, α = 89.385(7), β = 68.527(7), γ = 66.190(8)°; V = 1425.8(2) Å3, Z = 2, R = 0.0417, wR 2 = 0.0744.
AB - New copper(I) complex involving the flexible N2S2 Schiff-base ligand ca2dapte [Cu(ca2dapte)(NCS)], [ca 2dapte = N,N'-bis-(cinnamaldehyde)-1,2-di(o-iminophenylthio) ethane], has been synthesized and structurally characterized by X-ray diffraction analysis. The coordination polyhedron around the Cu(I) center is best described as a distorted tetrahedron. The flexible N2S2 Schiff-base ligand ca2dapte acts as a tridentate ligand via two S atoms and one N atom, while the NCS- ligand is coordinated to the metal ion through its nitrogen atom. Crystal data: space group P-1, a = 10.7486(7), b = 12.3737(13), c = 12.7578(11) Å, α = 89.385(7), β = 68.527(7), γ = 66.190(8)°; V = 1425.8(2) Å3, Z = 2, R = 0.0417, wR 2 = 0.0744.
KW - Copper (I) complex
KW - NS Schiff-base
KW - Tridentate coordination mode
KW - X-ray crystal structure
UR - http://www.scopus.com/inward/record.url?scp=79951682973&partnerID=8YFLogxK
U2 - 10.1007/s10870-010-9833-4
DO - 10.1007/s10870-010-9833-4
M3 - Article
SN - 1074-1542
VL - 41
SP - 39
EP - 43
JO - Journal of Chemical Crystallography
JF - Journal of Chemical Crystallography
IS - 1
ER -