Coupling Versus Substitution of Coordinated Ethylene with Iminooxosulfanes - Crystal-structure of [os(ch2ch2s(nso2c6h4me-4)o)cl(no)(pph3)2]

Max Herberhold; Anthony F. Hill; George R. Clark; Clifton E.F. Rickard; Warren R. Roper; Anthony H. Wright

doi:10.1021/om00112a034

Coupling Versus Substitution of Coordinated Ethylene with Iminooxosulfanes - Crystal-structure of [os(ch2ch2s(nso2c6h4me-4)o)cl(no)(pph3)2]

Max Herberhold
, Anthony F. Hill^*
, George R. Clark
, Clifton E.F. Rickard
, Warren R. Roper
, Anthony H. Wright

^*Corresponding author for this work

Research output: Contribution to journal › Comment/debate › peer-review

9 Citations (Scopus)

Abstract

The osmium ethylene complex [OsCf-(NO)(C₂H₄)(PPh₃)₂] reacts with ((p-tolylsulfonyl)imino)oxo-λ⁴-sulfane (O=S=NSO₂C₆H₄Me-₄) by either substitution of or electrophilic attack at the coordinated ethylene ligand to provide respectively [OsCI(NO)(η²-OSNSO₂G₆H₄Me-4)(PPh₃)₂] or the structurally characterized osmacycle [Os{CH₂CH₂S(=NSO₂C₆H₄Me-₄)O}CI-(NO)PPh₃)₂].

Original language	English
Pages (from-to)	2483-2484
Number of pages	2
Journal	Organometallics
Volume	8
Issue number	10
DOIs	https://doi.org/10.1021/om00112a034
Publication status	Published - Oct 1989
Externally published	Yes

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@article{3eafced75dec4bc0877259535946848a,

title = "Coupling Versus Substitution of Coordinated Ethylene with Iminooxosulfanes - Crystal-structure of [os(ch2ch2s(nso2c6h4me-4)o)cl(no)(pph3)2]",

abstract = "The osmium ethylene complex [OsCf-(NO)(C2H4)(PPh3)2] reacts with ((p-tolylsulfonyl)imino)oxo-λ4-sulfane (O=S=NSO2C6H4Me-4) by either substitution of or electrophilic attack at the coordinated ethylene ligand to provide respectively [OsCI(NO)(η2-OSNSO2G6H4Me-4)(PPh3)2] or the structurally characterized osmacycle [Os\{CH2CH2S(=NSO2C6H4Me-4)O\}CI-(NO)PPh3)2].",

author = "Max Herberhold and Hill, \{Anthony F.\} and Clark, \{George R.\} and Rickard, \{Clifton E.F.\} and Roper, \{Warren R.\} and Wright, \{Anthony H.\}",

year = "1989",

month = oct,

doi = "10.1021/om00112a034",

language = "English",

volume = "8",

pages = "2483--2484",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "10",

}

TY - JOUR

T1 - Coupling Versus Substitution of Coordinated Ethylene with Iminooxosulfanes - Crystal-structure of [os(ch2ch2s(nso2c6h4me-4)o)cl(no)(pph3)2]

AU - Herberhold, Max

AU - Hill, Anthony F.

AU - Clark, George R.

AU - Rickard, Clifton E.F.

AU - Roper, Warren R.

AU - Wright, Anthony H.

PY - 1989/10

Y1 - 1989/10

N2 - The osmium ethylene complex [OsCf-(NO)(C2H4)(PPh3)2] reacts with ((p-tolylsulfonyl)imino)oxo-λ4-sulfane (O=S=NSO2C6H4Me-4) by either substitution of or electrophilic attack at the coordinated ethylene ligand to provide respectively [OsCI(NO)(η2-OSNSO2G6H4Me-4)(PPh3)2] or the structurally characterized osmacycle [Os{CH2CH2S(=NSO2C6H4Me-4)O}CI-(NO)PPh3)2].

AB - The osmium ethylene complex [OsCf-(NO)(C2H4)(PPh3)2] reacts with ((p-tolylsulfonyl)imino)oxo-λ4-sulfane (O=S=NSO2C6H4Me-4) by either substitution of or electrophilic attack at the coordinated ethylene ligand to provide respectively [OsCI(NO)(η2-OSNSO2G6H4Me-4)(PPh3)2] or the structurally characterized osmacycle [Os{CH2CH2S(=NSO2C6H4Me-4)O}CI-(NO)PPh3)2].

UR - https://www.scopus.com/pages/publications/0642319159

U2 - 10.1021/om00112a034

DO - 10.1021/om00112a034

M3 - Comment/debate

AN - SCOPUS:0642319159

SN - 0276-7333

VL - 8

SP - 2483

EP - 2484

JO - Organometallics

JF - Organometallics

IS - 10

ER -

Coupling Versus Substitution of Coordinated Ethylene with Iminooxosulfanes - Crystal-structure of [os(ch2ch2s(nso2c6h4me-4)o)cl(no)(pph3)2]

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