CP-225,917 and CP-263,114 synthesis support studies: Testing a radical cyclization strategy for installation of the side-chains

Martin G. Banwell; Mark J. Coster; Alison J. Edwards; Markus Vögtle

doi:10.1071/CH02244

CP-225,917 and CP-263,114 synthesis support studies: Testing a radical cyclization strategy for installation of the side-chains

Martin G. Banwell, Mark J. Coster, Alison J. Edwards, Markus Vögtle

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The selenocarbonate (18) has been prepared and shown to react with hexabutyldistannane hydride/allyltributylstannane to give, via a radical cyclization/allylation sequence, the lactone (21) embodying vicinal and trans-related functionality likely to be appropriate for elaboration to the side-chains associated with the title compounds (1) and (2) (phomoidrides A and B).

Original language	English
Pages (from-to)	577-583
Number of pages	7
Journal	Australian Journal of Chemistry
Volume	56
Issue number	6
DOIs	https://doi.org/10.1071/CH02244
Publication status	Published - 2003

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10.1071/CH02244

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abstract = "The selenocarbonate (18) has been prepared and shown to react with hexabutyldistannane hydride/allyltributylstannane to give, via a radical cyclization/allylation sequence, the lactone (21) embodying vicinal and trans-related functionality likely to be appropriate for elaboration to the side-chains associated with the title compounds (1) and (2) (phomoidrides A and B).",

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AU - Coster, Mark J.

AU - Edwards, Alison J.

AU - Vögtle, Markus

PY - 2003

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AB - The selenocarbonate (18) has been prepared and shown to react with hexabutyldistannane hydride/allyltributylstannane to give, via a radical cyclization/allylation sequence, the lactone (21) embodying vicinal and trans-related functionality likely to be appropriate for elaboration to the side-chains associated with the title compounds (1) and (2) (phomoidrides A and B).

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DO - 10.1071/CH02244

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JO - Australian Journal of Chemistry

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IS - 6

ER -

CP-225,917 and CP-263,114 synthesis support studies: Testing a radical cyclization strategy for installation of the side-chains

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