CP-225,917 and CP-263,114 synthesis support studies: Testing a radical cyclization strategy for installation of the side-chains

Martin G. Banwell; Mark J. Coster; Alison J. Edwards; Markus Vögtle

doi:10.1071/CH02244

CP-225,917 and CP-263,114 synthesis support studies: Testing a radical cyclization strategy for installation of the side-chains

Martin G. Banwell, Mark J. Coster, Alison J. Edwards, Markus Vögtle

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The selenocarbonate (18) has been prepared and shown to react with hexabutyldistannane hydride/allyltributylstannane to give, via a radical cyclization/allylation sequence, the lactone (21) embodying vicinal and trans-related functionality likely to be appropriate for elaboration to the side-chains associated with the title compounds (1) and (2) (phomoidrides A and B).

Original language	English
Pages (from-to)	577-583
Number of pages	7
Journal	Australian Journal of Chemistry
Volume	56
Issue number	6
DOIs	https://doi.org/10.1071/CH02244
Publication status	Published - 2003

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title = "CP-225,917 and CP-263,114 synthesis support studies: Testing a radical cyclization strategy for installation of the side-chains",

abstract = "The selenocarbonate (18) has been prepared and shown to react with hexabutyldistannane hydride/allyltributylstannane to give, via a radical cyclization/allylation sequence, the lactone (21) embodying vicinal and trans-related functionality likely to be appropriate for elaboration to the side-chains associated with the title compounds (1) and (2) (phomoidrides A and B).",

author = "Banwell, \{Martin G.\} and Coster, \{Mark J.\} and Edwards, \{Alison J.\} and Markus V{\"o}gtle",

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journal = "Australian Journal of Chemistry",

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T2 - Testing a radical cyclization strategy for installation of the side-chains

AU - Banwell, Martin G.

AU - Coster, Mark J.

AU - Edwards, Alison J.

AU - Vögtle, Markus

PY - 2003

Y1 - 2003

N2 - The selenocarbonate (18) has been prepared and shown to react with hexabutyldistannane hydride/allyltributylstannane to give, via a radical cyclization/allylation sequence, the lactone (21) embodying vicinal and trans-related functionality likely to be appropriate for elaboration to the side-chains associated with the title compounds (1) and (2) (phomoidrides A and B).

AB - The selenocarbonate (18) has been prepared and shown to react with hexabutyldistannane hydride/allyltributylstannane to give, via a radical cyclization/allylation sequence, the lactone (21) embodying vicinal and trans-related functionality likely to be appropriate for elaboration to the side-chains associated with the title compounds (1) and (2) (phomoidrides A and B).

UR - https://www.scopus.com/pages/publications/0037810393

U2 - 10.1071/CH02244

DO - 10.1071/CH02244

M3 - Article

SN - 0004-9425

VL - 56

SP - 577

EP - 583

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 6

ER -

CP-225,917 and CP-263,114 synthesis support studies: Testing a radical cyclization strategy for installation of the side-chains

Abstract

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