Crystal growth of novel lanthanide-containing platinates K 4[Ln 6Pt 2O 15] (Ln = La, Pr, Nd, Sm) with a unique framework structure

Hans Conrad Zur Loye; Tara J. Hansen; Qingbiao Zhao; Samuel J. Mugavero; Ray L. Withers; Mark D. Smith

doi:10.1021/ic801789e

Crystal growth of novel lanthanide-containing platinates K ₄[Ln ₆Pt ₂O ₁₅] (Ln = La, Pr, Nd, Sm) with a unique framework structure

Hans Conrad Zur Loye, Tara J. Hansen, Qingbiao Zhao, Samuel J. Mugavero, Ray L. Withers, Mark D. Smith

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Crystals of a new family of lanthanide-containing platinum oxides with a unique framework structure were grown out of molten hydroxide fluxes. The structure consists of a crystallographically well-behaved [Ln ₆Pt ₂O ₁₅] ^4- framework permeated by channels filled with disordered atoms along the [100] and equivalent directions. Open-channel structures are rare in oxides and apparently unknown in platinate chemistry.

Original language	English
Pages (from-to)	414-416
Number of pages	3
Journal	Inorganic Chemistry
Volume	48
Issue number	2
DOIs	https://doi.org/10.1021/ic801789e
Publication status	Published - 19 Jan 2009

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abstract = "Crystals of a new family of lanthanide-containing platinum oxides with a unique framework structure were grown out of molten hydroxide fluxes. The structure consists of a crystallographically well-behaved [Ln 6Pt 2O 15] 4- framework permeated by channels filled with disordered atoms along the [100] and equivalent directions. Open-channel structures are rare in oxides and apparently unknown in platinate chemistry.",

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T1 - Crystal growth of novel lanthanide-containing platinates K 4[Ln 6Pt 2O 15] (Ln = La, Pr, Nd, Sm) with a unique framework structure

AU - Loye, Hans Conrad Zur

AU - Hansen, Tara J.

AU - Zhao, Qingbiao

AU - Mugavero, Samuel J.

AU - Withers, Ray L.

AU - Smith, Mark D.

PY - 2009/1/19

Y1 - 2009/1/19

N2 - Crystals of a new family of lanthanide-containing platinum oxides with a unique framework structure were grown out of molten hydroxide fluxes. The structure consists of a crystallographically well-behaved [Ln 6Pt 2O 15] 4- framework permeated by channels filled with disordered atoms along the [100] and equivalent directions. Open-channel structures are rare in oxides and apparently unknown in platinate chemistry.

AB - Crystals of a new family of lanthanide-containing platinum oxides with a unique framework structure were grown out of molten hydroxide fluxes. The structure consists of a crystallographically well-behaved [Ln 6Pt 2O 15] 4- framework permeated by channels filled with disordered atoms along the [100] and equivalent directions. Open-channel structures are rare in oxides and apparently unknown in platinate chemistry.

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U2 - 10.1021/ic801789e

DO - 10.1021/ic801789e

M3 - Article

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VL - 48

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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ER -

Crystal growth of novel lanthanide-containing platinates K ₄[Ln ₆Pt ₂O ₁₅] (Ln = La, Pr, Nd, Sm) with a unique framework structure

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