Cubic-Core Hexagonal-Branch Mechanism to Synthesize Bimetallic Branched and Faceted Pd-Ru Nanoparticles for Oxygen Evolution Reaction Electrocatalysis

Lucy Gloag; Tania M. Benedetti; Soshan Cheong; Christopher E. Marjo; J. Justin Gooding; Richard D. Tilley

doi:10.1021/jacs.8b09402

Cubic-Core Hexagonal-Branch Mechanism to Synthesize Bimetallic Branched and Faceted Pd-Ru Nanoparticles for Oxygen Evolution Reaction Electrocatalysis

Lucy Gloag, Tania M. Benedetti, Soshan Cheong, Christopher E. Marjo, J. Justin Gooding, Richard D. Tilley^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

85 Citations (SciVal)

Abstract

A major synthetic challenge is to make metal nanoparticles with nanosized branches and well-defined facets for high-performance catalysts. Herein, we introduce a mechanism that uses the growth of hexagonal crystal structured branches off cubic crystal structured core nanoparticles. We control the growth to form Pd-core Ru-branch nanoparticles that have nanosized branches with low index Ru facets. We demonstrate that the branched and faceted structural features of the Pd-Ru nanoparticles retain high catalytic activity while also achieving high stability for the oxygen evolution reaction.

Original language	English
Pages (from-to)	12760-12764
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	140
Issue number	40
DOIs	https://doi.org/10.1021/jacs.8b09402
Publication status	Published - 10 Oct 2018
Externally published	Yes

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title = "Cubic-Core Hexagonal-Branch Mechanism to Synthesize Bimetallic Branched and Faceted Pd-Ru Nanoparticles for Oxygen Evolution Reaction Electrocatalysis",

abstract = "A major synthetic challenge is to make metal nanoparticles with nanosized branches and well-defined facets for high-performance catalysts. Herein, we introduce a mechanism that uses the growth of hexagonal crystal structured branches off cubic crystal structured core nanoparticles. We control the growth to form Pd-core Ru-branch nanoparticles that have nanosized branches with low index Ru facets. We demonstrate that the branched and faceted structural features of the Pd-Ru nanoparticles retain high catalytic activity while also achieving high stability for the oxygen evolution reaction.",

author = "Lucy Gloag and Benedetti, {Tania M.} and Soshan Cheong and Marjo, {Christopher E.} and Gooding, {J. Justin} and Tilley, {Richard D.}",

note = "Publisher Copyright: Copyright {\textcopyright} 2018 American Chemical Society.",

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AU - Gloag, Lucy

AU - Benedetti, Tania M.

AU - Cheong, Soshan

AU - Marjo, Christopher E.

AU - Gooding, J. Justin

AU - Tilley, Richard D.

PY - 2018/10/10

Y1 - 2018/10/10

N2 - A major synthetic challenge is to make metal nanoparticles with nanosized branches and well-defined facets for high-performance catalysts. Herein, we introduce a mechanism that uses the growth of hexagonal crystal structured branches off cubic crystal structured core nanoparticles. We control the growth to form Pd-core Ru-branch nanoparticles that have nanosized branches with low index Ru facets. We demonstrate that the branched and faceted structural features of the Pd-Ru nanoparticles retain high catalytic activity while also achieving high stability for the oxygen evolution reaction.

AB - A major synthetic challenge is to make metal nanoparticles with nanosized branches and well-defined facets for high-performance catalysts. Herein, we introduce a mechanism that uses the growth of hexagonal crystal structured branches off cubic crystal structured core nanoparticles. We control the growth to form Pd-core Ru-branch nanoparticles that have nanosized branches with low index Ru facets. We demonstrate that the branched and faceted structural features of the Pd-Ru nanoparticles retain high catalytic activity while also achieving high stability for the oxygen evolution reaction.

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U2 - 10.1021/jacs.8b09402

DO - 10.1021/jacs.8b09402

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JF - Journal of the American Chemical Society

IS - 40

ER -

Cubic-Core Hexagonal-Branch Mechanism to Synthesize Bimetallic Branched and Faceted Pd-Ru Nanoparticles for Oxygen Evolution Reaction Electrocatalysis

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