Cycloaurated complexes of aryl carbanions: Digold(I), Digold(II) and beyond

Nedaossadat Mirzadeh; Martin A. Bennett; Suresh K. Bhargava

doi:10.1016/j.ccr.2013.02.011

Cycloaurated complexes of aryl carbanions: Digold(I), Digold(II) and beyond

Nedaossadat Mirzadeh, Martin A. Bennett, Suresh K. Bhargava^*

^*Corresponding author for this work

Research output: Contribution to journal › Review article › peer-review

39 Citations (Scopus)

Abstract

Dinuclear gold(I) complexes containing a pair of bridging ligands represent a special class of gold compounds. An important aspect of their chemistry is the ability to undergo oxidative addition reactions to give isolable dinuclear gold(II) complexes, which are the most abundant representatives of gold(II) species. The present review concentrates on a particular class of aryl carbanionic ligand of the type 2-C₆R₄ER'₂ [R=H, F; E=P, As; R'=alkyl, phenyl] and aims to provide an up-to-date account of the existing literature on the stability and reactivity of their dinuclear gold complexes.

Original language	English
Pages (from-to)	2250-2273
Number of pages	24
Journal	Coordination Chemistry Reviews
Volume	257
Issue number	15-16
DOIs	https://doi.org/10.1016/j.ccr.2013.02.011
Publication status	Published - Aug 2013

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title = "Cycloaurated complexes of aryl carbanions: Digold(I), Digold(II) and beyond",

abstract = "Dinuclear gold(I) complexes containing a pair of bridging ligands represent a special class of gold compounds. An important aspect of their chemistry is the ability to undergo oxidative addition reactions to give isolable dinuclear gold(II) complexes, which are the most abundant representatives of gold(II) species. The present review concentrates on a particular class of aryl carbanionic ligand of the type 2-C6R4ER'2 [R=H, F; E=P, As; R'=alkyl, phenyl] and aims to provide an up-to-date account of the existing literature on the stability and reactivity of their dinuclear gold complexes.",

keywords = "Aryl carbanions, Cycloaurated, Dinuclear gold, Gold(I), Gold(II), Gold(III)",

author = "Nedaossadat Mirzadeh and Bennett, {Martin A.} and Bhargava, {Suresh K.}",

year = "2013",

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language = "English",

volume = "257",

pages = "2250--2273",

journal = "Coordination Chemistry Reviews",

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T1 - Cycloaurated complexes of aryl carbanions

T2 - Digold(I), Digold(II) and beyond

AU - Mirzadeh, Nedaossadat

AU - Bennett, Martin A.

AU - Bhargava, Suresh K.

PY - 2013/8

Y1 - 2013/8

N2 - Dinuclear gold(I) complexes containing a pair of bridging ligands represent a special class of gold compounds. An important aspect of their chemistry is the ability to undergo oxidative addition reactions to give isolable dinuclear gold(II) complexes, which are the most abundant representatives of gold(II) species. The present review concentrates on a particular class of aryl carbanionic ligand of the type 2-C6R4ER'2 [R=H, F; E=P, As; R'=alkyl, phenyl] and aims to provide an up-to-date account of the existing literature on the stability and reactivity of their dinuclear gold complexes.

AB - Dinuclear gold(I) complexes containing a pair of bridging ligands represent a special class of gold compounds. An important aspect of their chemistry is the ability to undergo oxidative addition reactions to give isolable dinuclear gold(II) complexes, which are the most abundant representatives of gold(II) species. The present review concentrates on a particular class of aryl carbanionic ligand of the type 2-C6R4ER'2 [R=H, F; E=P, As; R'=alkyl, phenyl] and aims to provide an up-to-date account of the existing literature on the stability and reactivity of their dinuclear gold complexes.

KW - Aryl carbanions

KW - Cycloaurated

KW - Dinuclear gold

KW - Gold(I)

KW - Gold(II)

KW - Gold(III)

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U2 - 10.1016/j.ccr.2013.02.011

DO - 10.1016/j.ccr.2013.02.011

M3 - Review article

SN - 0010-8545

VL - 257

SP - 2250

EP - 2273

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

IS - 15-16

ER -

Cycloaurated complexes of aryl carbanions: Digold(I), Digold(II) and beyond

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