TY - JOUR
T1 - Cyclopentadienyl-Ruthenium and -Osmium Chemistry. XXIII Synthesis and Reactions of Some Hydrido Complexes Containing Ruthenium or Osmium, and Related Chemistry
AU - Bruce, Michael I.
AU - Humphrey, Mark G.
AU - Geoffrey Swincer, A.
AU - Wallis, Robert C.
PY - 1984
Y1 - 1984
N2 - The hydrido complexes HM(PPh3)2(η-C5H5) (M = Ru, Os), HFe(dppe) (η-C5H5), HRu(L2)(η-C5H5) (L2 = dppe, dppmordpae), HRu(AsPh3)2(η-C5H5), HRu(L)(PPh3)(η-C5H5) [L = CNBut, P(OPh)3] have been obtained from reactions between the analogous chloro complexes and NaOMe/MeOH; RuCl[P(OPh)3]2(η-C5H5) affords the cyclometallated under these conditions. Reactions between HRu(PPh3)2(η-C-H5) and HX or CHX3 (X = Cl, Br, I) afford the corresponding halo complexes RuX(PPh3)2(η-C5H5); CS2 reacts with HRuL2(η-C5H5) (L = PPh3, L2 = dppe) to give the corresponding dithioformato derivatives. Ligand-exchange reactions of HRu(PPh3)2(η-C5H5) with CO or dppe proceed with difficulty at temperatures of c. 150-200°C in an autoclave.
AB - The hydrido complexes HM(PPh3)2(η-C5H5) (M = Ru, Os), HFe(dppe) (η-C5H5), HRu(L2)(η-C5H5) (L2 = dppe, dppmordpae), HRu(AsPh3)2(η-C5H5), HRu(L)(PPh3)(η-C5H5) [L = CNBut, P(OPh)3] have been obtained from reactions between the analogous chloro complexes and NaOMe/MeOH; RuCl[P(OPh)3]2(η-C5H5) affords the cyclometallated under these conditions. Reactions between HRu(PPh3)2(η-C-H5) and HX or CHX3 (X = Cl, Br, I) afford the corresponding halo complexes RuX(PPh3)2(η-C5H5); CS2 reacts with HRuL2(η-C5H5) (L = PPh3, L2 = dppe) to give the corresponding dithioformato derivatives. Ligand-exchange reactions of HRu(PPh3)2(η-C5H5) with CO or dppe proceed with difficulty at temperatures of c. 150-200°C in an autoclave.
UR - http://www.scopus.com/inward/record.url?scp=0001281176&partnerID=8YFLogxK
U2 - 10.1071/CH9841747
DO - 10.1071/CH9841747
M3 - Article
AN - SCOPUS:0001281176
SN - 0004-9425
VL - 37
SP - 1747
EP - 1755
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
IS - 8
ER -