Cyclopentadienyl-Ruthenium and -Osmium Chemistry. XXIII Synthesis and Reactions of Some Hydrido Complexes Containing Ruthenium or Osmium, and Related Chemistry

Michael I. Bruce; Mark G. Humphrey; A. Geoffrey Swincer; Robert C. Wallis

doi:10.1071/CH9841747

Cyclopentadienyl-Ruthenium and -Osmium Chemistry. XXIII Synthesis and Reactions of Some Hydrido Complexes Containing Ruthenium or Osmium, and Related Chemistry

Michael I. Bruce^*, Mark G. Humphrey, A. Geoffrey Swincer, Robert C. Wallis

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

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Abstract

The hydrido complexes HM(PPh₃)₂(η-C₅H5) (M = Ru, Os), HFe(dppe) (η-C₅H₅), HRu(L₂)(η-C₅H₅) (L₂ = dppe, dppmordpae), HRu(AsPh₃)₂(η-C₅H₅), HRu(L)(PPh₃)(η-C₅H5) [L = CNBut, P(OPh)₃] have been obtained from reactions between the analogous chloro complexes and NaOMe/MeOH; RuCl[P(OPh)₃]₂(η-C₅H₅) affords the cyclometallated under these conditions. Reactions between HRu(PPh₃)₂(η-C-H₅) and HX or CHX₃ (X = Cl, Br, I) afford the corresponding halo complexes RuX(PPh₃)₂(η-C₅H₅); CS₂ reacts with HRuL₂(η-C₅H₅) (L = PPh₃, L₂ = dppe) to give the corresponding dithioformato derivatives. Ligand-exchange reactions of HRu(PPh₃)₂(η-C₅H₅) with CO or dppe proceed with difficulty at temperatures of c. 150-200°C in an autoclave.

Original language	English
Pages (from-to)	1747-1755
Number of pages	9
Journal	Australian Journal of Chemistry
Volume	37
Issue number	8
DOIs	https://doi.org/10.1071/CH9841747
Publication status	Published - 1984
Externally published	Yes

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@article{08449548162e45d4995c4d3d3b23649a,

title = "Cyclopentadienyl-Ruthenium and -Osmium Chemistry. XXIII Synthesis and Reactions of Some Hydrido Complexes Containing Ruthenium or Osmium, and Related Chemistry",

abstract = "The hydrido complexes HM(PPh3)2(η-C5H5) (M = Ru, Os), HFe(dppe) (η-C5H5), HRu(L2)(η-C5H5) (L2 = dppe, dppmordpae), HRu(AsPh3)2(η-C5H5), HRu(L)(PPh3)(η-C5H5) [L = CNBut, P(OPh)3] have been obtained from reactions between the analogous chloro complexes and NaOMe/MeOH; RuCl[P(OPh)3]2(η-C5H5) affords the cyclometallated under these conditions. Reactions between HRu(PPh3)2(η-C-H5) and HX or CHX3 (X = Cl, Br, I) afford the corresponding halo complexes RuX(PPh3)2(η-C5H5); CS2 reacts with HRuL2(η-C5H5) (L = PPh3, L2 = dppe) to give the corresponding dithioformato derivatives. Ligand-exchange reactions of HRu(PPh3)2(η-C5H5) with CO or dppe proceed with difficulty at temperatures of c. 150-200°C in an autoclave.",

author = "Bruce, \{Michael I.\} and Humphrey, \{Mark G.\} and \{Geoffrey Swincer\}, A. and Wallis, \{Robert C.\}",

year = "1984",

doi = "10.1071/CH9841747",

language = "English",

volume = "37",

pages = "1747--1755",

journal = "Australian Journal of Chemistry",

issn = "0004-9425",

publisher = "CSIRO",

number = "8",

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T1 - Cyclopentadienyl-Ruthenium and -Osmium Chemistry. XXIII Synthesis and Reactions of Some Hydrido Complexes Containing Ruthenium or Osmium, and Related Chemistry

AU - Bruce, Michael I.

AU - Humphrey, Mark G.

AU - Geoffrey Swincer, A.

AU - Wallis, Robert C.

PY - 1984

Y1 - 1984

N2 - The hydrido complexes HM(PPh3)2(η-C5H5) (M = Ru, Os), HFe(dppe) (η-C5H5), HRu(L2)(η-C5H5) (L2 = dppe, dppmordpae), HRu(AsPh3)2(η-C5H5), HRu(L)(PPh3)(η-C5H5) [L = CNBut, P(OPh)3] have been obtained from reactions between the analogous chloro complexes and NaOMe/MeOH; RuCl[P(OPh)3]2(η-C5H5) affords the cyclometallated under these conditions. Reactions between HRu(PPh3)2(η-C-H5) and HX or CHX3 (X = Cl, Br, I) afford the corresponding halo complexes RuX(PPh3)2(η-C5H5); CS2 reacts with HRuL2(η-C5H5) (L = PPh3, L2 = dppe) to give the corresponding dithioformato derivatives. Ligand-exchange reactions of HRu(PPh3)2(η-C5H5) with CO or dppe proceed with difficulty at temperatures of c. 150-200°C in an autoclave.

AB - The hydrido complexes HM(PPh3)2(η-C5H5) (M = Ru, Os), HFe(dppe) (η-C5H5), HRu(L2)(η-C5H5) (L2 = dppe, dppmordpae), HRu(AsPh3)2(η-C5H5), HRu(L)(PPh3)(η-C5H5) [L = CNBut, P(OPh)3] have been obtained from reactions between the analogous chloro complexes and NaOMe/MeOH; RuCl[P(OPh)3]2(η-C5H5) affords the cyclometallated under these conditions. Reactions between HRu(PPh3)2(η-C-H5) and HX or CHX3 (X = Cl, Br, I) afford the corresponding halo complexes RuX(PPh3)2(η-C5H5); CS2 reacts with HRuL2(η-C5H5) (L = PPh3, L2 = dppe) to give the corresponding dithioformato derivatives. Ligand-exchange reactions of HRu(PPh3)2(η-C5H5) with CO or dppe proceed with difficulty at temperatures of c. 150-200°C in an autoclave.

UR - https://www.scopus.com/pages/publications/0001281176

U2 - 10.1071/CH9841747

DO - 10.1071/CH9841747

M3 - Article

AN - SCOPUS:0001281176

SN - 0004-9425

VL - 37

SP - 1747

EP - 1755

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 8

ER -

Cyclopentadienyl-Ruthenium and -Osmium Chemistry. XXIII Synthesis and Reactions of Some Hydrido Complexes Containing Ruthenium or Osmium, and Related Chemistry

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