TY - JOUR
T1 - Decacarbonylbis(methylcyclopentadienyl)-tetrahedro-diiridiumdimolybdenum and decacarbonylbis (tetra-methylcyclopentadienyl)-tetrahedro-diiridiumdimolybdenum dichloromethane hemisolvate
AU - Lucas, Nigel T.
AU - Humphrey, Mark G.
PY - 2002/3
Y1 - 2002/3
N2 - The two title compounds, [Mo2Ir2 (C6H7)2(CO)10] and [Mo2Ir2(C9H13)2 (CO)10]·0.5CH2Cl2, respectively, or collectively [Mo2Ir2(μ-CO)3 (CO)7(η5-C5H5-n Men)2] (n = 1 or 4), have a pseudo-tetrahedral Mo2Ir2 core geometry, an η5-C5H5-nMen group ligating each Mo atom, bridging carbonyls spanning the edges of an MoIr2 face and seven terminally bound carbonyl groups.
AB - The two title compounds, [Mo2Ir2 (C6H7)2(CO)10] and [Mo2Ir2(C9H13)2 (CO)10]·0.5CH2Cl2, respectively, or collectively [Mo2Ir2(μ-CO)3 (CO)7(η5-C5H5-n Men)2] (n = 1 or 4), have a pseudo-tetrahedral Mo2Ir2 core geometry, an η5-C5H5-nMen group ligating each Mo atom, bridging carbonyls spanning the edges of an MoIr2 face and seven terminally bound carbonyl groups.
UR - http://www.scopus.com/inward/record.url?scp=0036502892&partnerID=8YFLogxK
U2 - 10.1107/S0108270102000057
DO - 10.1107/S0108270102000057
M3 - Article
SN - 0108-2701
VL - 58
SP - m171-m173
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 3
ER -