Decacarbonylbis(methylcyclopentadienyl)-tetrahedro-diiridiumdimolybdenum and decacarbonylbis (tetra-methylcyclopentadienyl)-tetrahedro-diiridiumdimolybdenum dichloromethane hemisolvate

Nigel T. Lucas; Mark G. Humphrey

doi:10.1107/S0108270102000057

Decacarbonylbis(methylcyclopentadienyl)-tetrahedro-diiridiumdimolybdenum and decacarbonylbis (tetra-methylcyclopentadienyl)-tetrahedro-diiridiumdimolybdenum dichloromethane hemisolvate

Nigel T. Lucas
, Mark G. Humphrey^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The two title compounds, [Mo₂Ir₂ (C₆H₇)₂(CO)₁₀] and [Mo₂Ir₂(C₉H₁₃)₂ (CO)₁₀]·0.5CH₂Cl₂, respectively, or collectively [Mo₂Ir₂(μ-CO)₃ (CO)₇(η⁵-C₅H_5-n Me_n)₂] (n = 1 or 4), have a pseudo-tetrahedral Mo₂Ir₂ core geometry, an η⁵-C₅H_5-nMe_n group ligating each Mo atom, bridging carbonyls spanning the edges of an MoIr₂ face and seven terminally bound carbonyl groups.

Original language	English
Pages (from-to)	m171-m173
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	58
Issue number	3
DOIs	https://doi.org/10.1107/S0108270102000057
Publication status	Published - Mar 2002

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@article{0ebc7abaab4a49a8bf18589163bd8a65,

title = "Decacarbonylbis(methylcyclopentadienyl)-tetrahedro-diiridiumdimolybdenum and decacarbonylbis (tetra-methylcyclopentadienyl)-tetrahedro-diiridiumdimolybdenum dichloromethane hemisolvate",

abstract = "The two title compounds, [Mo2Ir2 (C6H7)2(CO)10] and [Mo2Ir2(C9H13)2 (CO)10]·0.5CH2Cl2, respectively, or collectively [Mo2Ir2(μ-CO)3 (CO)7(η5-C5H5-n Men)2] (n = 1 or 4), have a pseudo-tetrahedral Mo2Ir2 core geometry, an η5-C5H5-nMen group ligating each Mo atom, bridging carbonyls spanning the edges of an MoIr2 face and seven terminally bound carbonyl groups.",

author = "Lucas, \{Nigel T.\} and Humphrey, \{Mark G.\}",

year = "2002",

month = mar,

doi = "10.1107/S0108270102000057",

language = "English",

volume = "58",

pages = "m171--m173",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "3",

}

Decacarbonylbis(methylcyclopentadienyl)-tetrahedro-diiridiumdimolybdenum and decacarbonylbis (tetra-methylcyclopentadienyl)-tetrahedro-diiridiumdimolybdenum dichloromethane hemisolvate. / Lucas, Nigel T.; Humphrey, Mark G.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 58, No. 3, 03.2002, p. m171-m173.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Decacarbonylbis(methylcyclopentadienyl)-tetrahedro-diiridiumdimolybdenum and decacarbonylbis (tetra-methylcyclopentadienyl)-tetrahedro-diiridiumdimolybdenum dichloromethane hemisolvate

AU - Lucas, Nigel T.

AU - Humphrey, Mark G.

PY - 2002/3

Y1 - 2002/3

N2 - The two title compounds, [Mo2Ir2 (C6H7)2(CO)10] and [Mo2Ir2(C9H13)2 (CO)10]·0.5CH2Cl2, respectively, or collectively [Mo2Ir2(μ-CO)3 (CO)7(η5-C5H5-n Men)2] (n = 1 or 4), have a pseudo-tetrahedral Mo2Ir2 core geometry, an η5-C5H5-nMen group ligating each Mo atom, bridging carbonyls spanning the edges of an MoIr2 face and seven terminally bound carbonyl groups.

AB - The two title compounds, [Mo2Ir2 (C6H7)2(CO)10] and [Mo2Ir2(C9H13)2 (CO)10]·0.5CH2Cl2, respectively, or collectively [Mo2Ir2(μ-CO)3 (CO)7(η5-C5H5-n Men)2] (n = 1 or 4), have a pseudo-tetrahedral Mo2Ir2 core geometry, an η5-C5H5-nMen group ligating each Mo atom, bridging carbonyls spanning the edges of an MoIr2 face and seven terminally bound carbonyl groups.

UR - https://www.scopus.com/pages/publications/0036502892

U2 - 10.1107/S0108270102000057

DO - 10.1107/S0108270102000057

M3 - Article

SN - 0108-2701

VL - 58

SP - m171-m173

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 3

ER -

Decacarbonylbis(methylcyclopentadienyl)-tetrahedro-diiridiumdimolybdenum and decacarbonylbis (tetra-methylcyclopentadienyl)-tetrahedro-diiridiumdimolybdenum dichloromethane hemisolvate

Abstract

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