Decanuclear Cluster-Based Metal-Organic Framework with a (3,11)-Connected Topology and Highly Sensitive 2,4,6-Trinitrophenol Detection

Jinfang Zhang; Yuhang Liu; Jiaoyang Feng; Linpei Gong; Mark G. Humphrey; Chi Zhang

doi:10.1021/acs.inorgchem.9b00745

Decanuclear Cluster-Based Metal-Organic Framework with a (3,11)-Connected Topology and Highly Sensitive 2,4,6-Trinitrophenol Detection

Jinfang Zhang, Yuhang Liu, Jiaoyang Feng, Linpei Gong, Mark G. Humphrey, Chi Zhang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

44 Citations (Scopus)

Abstract

A 3D heterothiometallic cluster-based metal-organic framework was constructed from the new oligomeric decanuclear heterothiometallic building clusters [W₂(μ₃-S)₆(μ₄-S)₂Cu₈]⁴⁺, tetradentate 3-abpt units (3-abpt = 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole), and CN^- bridges. It possesses an unprecedented (3,11)-connected architecture, luminescence, and highly sensitive 2,4,6-trinitrophenol (TNP) sensing properties in both organic and aqueous media.

Original language	English
Pages (from-to)	9749-9755
Number of pages	7
Journal	Inorganic Chemistry
Volume	58
Issue number	15
DOIs	https://doi.org/10.1021/acs.inorgchem.9b00745
Publication status	Published - 5 Aug 2019

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title = "Decanuclear Cluster-Based Metal-Organic Framework with a (3,11)-Connected Topology and Highly Sensitive 2,4,6-Trinitrophenol Detection",

abstract = "A 3D heterothiometallic cluster-based metal-organic framework was constructed from the new oligomeric decanuclear heterothiometallic building clusters [W2(μ3-S)6(μ4-S)2Cu8]4+, tetradentate 3-abpt units (3-abpt = 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole), and CN- bridges. It possesses an unprecedented (3,11)-connected architecture, luminescence, and highly sensitive 2,4,6-trinitrophenol (TNP) sensing properties in both organic and aqueous media.",

author = "Jinfang Zhang and Yuhang Liu and Jiaoyang Feng and Linpei Gong and Humphrey, {Mark G.} and Chi Zhang",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = aug,

day = "5",

doi = "10.1021/acs.inorgchem.9b00745",

language = "English",

volume = "58",

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T1 - Decanuclear Cluster-Based Metal-Organic Framework with a (3,11)-Connected Topology and Highly Sensitive 2,4,6-Trinitrophenol Detection

AU - Zhang, Jinfang

AU - Liu, Yuhang

AU - Feng, Jiaoyang

AU - Gong, Linpei

AU - Humphrey, Mark G.

AU - Zhang, Chi

PY - 2019/8/5

Y1 - 2019/8/5

N2 - A 3D heterothiometallic cluster-based metal-organic framework was constructed from the new oligomeric decanuclear heterothiometallic building clusters [W2(μ3-S)6(μ4-S)2Cu8]4+, tetradentate 3-abpt units (3-abpt = 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole), and CN- bridges. It possesses an unprecedented (3,11)-connected architecture, luminescence, and highly sensitive 2,4,6-trinitrophenol (TNP) sensing properties in both organic and aqueous media.

AB - A 3D heterothiometallic cluster-based metal-organic framework was constructed from the new oligomeric decanuclear heterothiometallic building clusters [W2(μ3-S)6(μ4-S)2Cu8]4+, tetradentate 3-abpt units (3-abpt = 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole), and CN- bridges. It possesses an unprecedented (3,11)-connected architecture, luminescence, and highly sensitive 2,4,6-trinitrophenol (TNP) sensing properties in both organic and aqueous media.

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U2 - 10.1021/acs.inorgchem.9b00745

DO - 10.1021/acs.inorgchem.9b00745

M3 - Article

SN - 0020-1669

VL - 58

SP - 9749

EP - 9755

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 15

ER -

Decanuclear Cluster-Based Metal-Organic Framework with a (3,11)-Connected Topology and Highly Sensitive 2,4,6-Trinitrophenol Detection

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