Deeply dredged submarine HIMU glasses from the Tuvalu Islands, Polynesia: Implications for volatile budgets of recycled oceanic crust

M. G. Jackson*, K. T. Koga, A. Price, J. G. Konter, A. A.P. Koppers, V. A. Finlayson, K. Konrad, E. H. Hauri, A. Kylander-Clark, K. A. Kelley, M. A. Kendrick

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    25 Citations (Scopus)

    Abstract

    Ocean island basalts (OIB) with extremely radiogenic Pb-isotopic signatures are melts of a mantle component called HIMU (high μ, high 238U/204Pb). Until now, deeply dredged submarine HIMU glasses have not been available, which has inhibited complete geochemical (in particular, volatile element) characterization of the HIMU mantle. We report major, trace and volatile element abundances in a suite of deeply dredged glasses from the Tuvalu Islands. Three Tuvalu glasses with the most extreme HIMU signatures have F/Nd ratios (35.6±3.6) that are higher than the ratio (∼21) for global OIB and MORB, consistent with elevated F/Nd ratios in end-member HIMU Mangaia melt inclusions. The Tuvalu glasses with the most extreme HIMU composition have Cl/K (0.11-0.12), Br/Cl (0.0024), and I/Cl (5-6 × 10-5) ratios that preclude significant assimilation of seawater-derived Cl. The new HIMU glasses that are least degassed for H2O have low H2O/Ce ratios (75-84), similar to ratios identified in end-member OIB glasses with EM1 and EM2 signatures, but significantly lower than H2O/Ce ratios (119-245) previously measured in melt inclusions from Mangaia. CO2-H2O equilibrium solubility models suggest that these HIMU glasses (recovered in two different dredges at 2500-3600 m water depth) have eruption pressures of 295-400 bars. We argue that degassing is unlikely to significantly reduce the primary melt H2O. Thus, the lower H2O/Ce in the HIMU Tuvalu glasses is a mantle signature. We explore oceanic crust recycling as the origin of the low H2O/Ce (∼50-80) in the EM1, EM2, and HIMU mantle domains.

    Original languageEnglish
    Pages (from-to)3210-3234
    Number of pages25
    JournalGeochemistry, Geophysics, Geosystems
    Volume16
    Issue number9
    DOIs
    Publication statusPublished - 1 Sept 2015

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