Design of a solar thermochemical reactor for calcium oxide based carbon dioxide capture

Leanne Reich, Luke Melmoth, Robert Gresham, Terrence Simon, Wojciech Lipiński

    Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

    3 Citations (Scopus)

    Abstract

    An engineering design for a 1-kW dual-cavity solar-driven reactor to capture carbon dioxide via the calcium oxide based two-step carbonation-calcination cycle is presented. In the low temperature carbonation step, gas containing up to 15% carbon dioxide flows through a gas manifold and plenum into an annular reaction zone filled with calcium oxide particles. The carbon dioxide reacts with the calcium oxide, forming calcium carbonate. Carbon dioxide-depleted gas flows out of the reactor through a second gas manifold. In the high temperature calcination step, concentrated solar radiation enters the beam-up oriented, windowless reactor and is absorbed by the diathermal cavity wall, which transfers heat via conduction to the calcium carbonate particles formed in the previous step. The calcium carbonate dissociates into calcium oxide and carbon dioxide. Additional carbon dioxide is used as a sweep gas to ensure high purity carbon dioxide at the outlet. Mechanical and thermal analyses are conducted to refine an initial reactor design and identify potential design shortcomings. Numerically predicted temperature profiles in the reactor are presented and the final reactor design is established.

    Original languageEnglish
    Title of host publicationPhotovoltaics; Renewable-Non-Renewable Hybrid Power System; Smart Grid, Micro-Grid Concepts; Energy Storage; Solar Chemistry; Solar Heating and Cooling; Sustainable Cities and Communities, Transportation; Symposium on Integrated/Sustainable Building Equipment and Systems; Thermofluid Analysis of Energy Systems Including Exergy and Thermoeconomics; Wind Energy Systems and Technologies
    PublisherAmerican Society of Mechanical Engineers
    ISBN (Electronic)9780791856857
    DOIs
    Publication statusPublished - 2015
    EventASME 2015 9th International Conference on Energy Sustainability, ES 2015, collocated with the ASME 2015 Power Conference, the ASME 2015 13th International Conference on Fuel Cell Science, Engineering and Technology, and the ASME 2015 Nuclear Forum - San Diego, United States
    Duration: 28 Jun 20152 Jul 2015

    Publication series

    NameASME 2015 9th International Conference on Energy Sustainability, ES 2015, collocated with the ASME 2015 Power Conference, the ASME 2015 13th International Conference on Fuel Cell Science, Engineering and Technology, and the ASME 2015 Nuclear Forum
    Volume2

    Conference

    ConferenceASME 2015 9th International Conference on Energy Sustainability, ES 2015, collocated with the ASME 2015 Power Conference, the ASME 2015 13th International Conference on Fuel Cell Science, Engineering and Technology, and the ASME 2015 Nuclear Forum
    Country/TerritoryUnited States
    CitySan Diego
    Period28/06/152/07/15

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