Determination of coupled solvent mass in quartz crystal microbalance measurements using deuterated solvents

Vincent S.J. Craig; Mark Plunkett

doi:10.1016/S0021-9797(03)00210-8

Determination of coupled solvent mass in quartz crystal microbalance measurements using deuterated solvents

Vincent S.J. Craig^*, Mark Plunkett

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

58 Citations (Scopus)

Abstract

A simple method is described for determining of the contribution of hydrodynamically coupled solvent to the adsorbed film mass determined in a quartz crystal microbalance (QCM) when operated in liquid. The method requires no additional apparatus and utilizes the change in QCM resonant frequency response between measurements made in nondeuterated and deuterated solvents. The mass of coupled water in a polymer film has been determined and is found to agree with that determined by XPS analysis of the dried polymer film.

Original language	English
Pages (from-to)	126-129
Number of pages	4
Journal	Journal of Colloid and Interface Science
Volume	262
Issue number	1
DOIs	https://doi.org/10.1016/S0021-9797(03)00210-8
Publication status	Published - 1 Jun 2003

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10.1016/S0021-9797(03)00210-8

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title = "Determination of coupled solvent mass in quartz crystal microbalance measurements using deuterated solvents",

abstract = "A simple method is described for determining of the contribution of hydrodynamically coupled solvent to the adsorbed film mass determined in a quartz crystal microbalance (QCM) when operated in liquid. The method requires no additional apparatus and utilizes the change in QCM resonant frequency response between measurements made in nondeuterated and deuterated solvents. The mass of coupled water in a polymer film has been determined and is found to agree with that determined by XPS analysis of the dried polymer film.",

keywords = "Coupled solvent, Coupled water, Deuterated solvent, Deuterated water, Quartz crystal microbalance",

author = "Craig, {Vincent S.J.} and Mark Plunkett",

year = "2003",

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doi = "10.1016/S0021-9797(03)00210-8",

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T1 - Determination of coupled solvent mass in quartz crystal microbalance measurements using deuterated solvents

AU - Craig, Vincent S.J.

AU - Plunkett, Mark

PY - 2003/6/1

Y1 - 2003/6/1

N2 - A simple method is described for determining of the contribution of hydrodynamically coupled solvent to the adsorbed film mass determined in a quartz crystal microbalance (QCM) when operated in liquid. The method requires no additional apparatus and utilizes the change in QCM resonant frequency response between measurements made in nondeuterated and deuterated solvents. The mass of coupled water in a polymer film has been determined and is found to agree with that determined by XPS analysis of the dried polymer film.

AB - A simple method is described for determining of the contribution of hydrodynamically coupled solvent to the adsorbed film mass determined in a quartz crystal microbalance (QCM) when operated in liquid. The method requires no additional apparatus and utilizes the change in QCM resonant frequency response between measurements made in nondeuterated and deuterated solvents. The mass of coupled water in a polymer film has been determined and is found to agree with that determined by XPS analysis of the dried polymer film.

KW - Coupled solvent

KW - Coupled water

KW - Deuterated solvent

KW - Deuterated water

KW - Quartz crystal microbalance

UR - http://www.scopus.com/inward/record.url?scp=0037690482&partnerID=8YFLogxK

U2 - 10.1016/S0021-9797(03)00210-8

DO - 10.1016/S0021-9797(03)00210-8

M3 - Article

SN - 0021-9797

VL - 262

SP - 126

EP - 129

JO - Journal of Colloid and Interface Science

JF - Journal of Colloid and Interface Science

IS - 1

ER -

Determination of coupled solvent mass in quartz crystal microbalance measurements using deuterated solvents

Abstract

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