DI(Carbido)Tetracosa(Carbonyl)-Decaruthenate(2-) Salts

Michael L. Bruce; Aurora Castro; Paul A. Humphrey; Peter M. Maitlis; Natasha N. Zaitseva; Lydie Viau; Mark G. Humphrey

doi:10.1002/9781118744994.ch23

DI(Carbido)Tetracosa(Carbonyl)-Decaruthenate(2-) Salts

Michael L. Bruce^*, Aurora Castro, Paul A. Humphrey, Peter M. Maitlis, Natasha N. Zaitseva, Lydie Viau, Mark G. Humphrey

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

Abstract

For the metal ruthenium, many examples of clusters with different nuclearity are known. The Ru10C2 cluster is formed by edge sharing of two Ru6C clusters. This chapter describes a synthesis of the decanuclear anion [Ru10C2(CO)24]2- from Ru3(CO)12 and calcium carbide in up to 50% yield. The chapter discusses the procedures and properties of calcium di(carbido)tetracosa(carbonyl) decaruthenium(2-) and BIS(triphenylphosphoranylidene)ammonium di (carbido)tetracosa(carbonyl)decaruthenium(2-).

Original language	English
Title of host publication	Inorganic Syntheses
Publisher	Wiley-Blackwell
Pages	126-128
Number of pages	3
Volume	36
ISBN (Electronic)	9781118744994
ISBN (Print)	9781118744871
DOIs	https://doi.org/10.1002/9781118744994.ch23
Publication status	Published - 12 May 2014

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title = "DI(Carbido)Tetracosa(Carbonyl)-Decaruthenate(2-) Salts",

abstract = "For the metal ruthenium, many examples of clusters with different nuclearity are known. The Ru10C2 cluster is formed by edge sharing of two Ru6C clusters. This chapter describes a synthesis of the decanuclear anion [Ru10C2(CO)24]2- from Ru3(CO)12 and calcium carbide in up to 50% yield. The chapter discusses the procedures and properties of calcium di(carbido)tetracosa(carbonyl) decaruthenium(2-) and BIS(triphenylphosphoranylidene)ammonium di (carbido)tetracosa(carbonyl)decaruthenium(2-).",

keywords = "Calcium di(carbido)tetracosa(carbonyl) decaruthenium(2-), Di(Carbido)tetracosa(Carbonyl) decaruthenium(2-) salts, Ruthenium",

author = "Bruce, {Michael L.} and Aurora Castro and Humphrey, {Paul A.} and Maitlis, {Peter M.} and Zaitseva, {Natasha N.} and Lydie Viau and Humphrey, {Mark G.}",

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doi = "10.1002/9781118744994.ch23",

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T1 - DI(Carbido)Tetracosa(Carbonyl)-Decaruthenate(2-) Salts

AU - Bruce, Michael L.

AU - Castro, Aurora

AU - Humphrey, Paul A.

AU - Maitlis, Peter M.

AU - Zaitseva, Natasha N.

AU - Viau, Lydie

AU - Humphrey, Mark G.

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AB - For the metal ruthenium, many examples of clusters with different nuclearity are known. The Ru10C2 cluster is formed by edge sharing of two Ru6C clusters. This chapter describes a synthesis of the decanuclear anion [Ru10C2(CO)24]2- from Ru3(CO)12 and calcium carbide in up to 50% yield. The chapter discusses the procedures and properties of calcium di(carbido)tetracosa(carbonyl) decaruthenium(2-) and BIS(triphenylphosphoranylidene)ammonium di (carbido)tetracosa(carbonyl)decaruthenium(2-).

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KW - Di(Carbido)tetracosa(Carbonyl) decaruthenium(2-) salts

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ER -

DI(Carbido)Tetracosa(Carbonyl)-Decaruthenate(2-) Salts

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