Dichotomy between palladium(II)-tin(II) and palladium(0)-tin(IV) in complexes of a Sn,As-based chelate ligand

Nedaossadat Mirzadeh; Martin Bennett; Jörg Wagler; Erik Wächtler; Birgit Gerke; Rainer Pöttgen; Suresh Bhargava

doi:10.1002/ejic.201300115

Dichotomy between palladium(II)-tin(II) and palladium(0)-tin(IV) in complexes of a Sn,As-based chelate ligand

Nedaossadat Mirzadeh, Martin Bennett, Jörg Wagler, Erik Wächtler, Birgit Gerke, Rainer Pöttgen, Suresh Bhargava^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

A dinuclear Pd-Sn bonded complex is reported, in which the interaction of the formally tin(II)-based ligand, [2-MeBrSnC₆F₄AsPh ₂]^-, with palladium appears to be best described as Pd^I-Sn^III or Pd⁰-Sn^IV.

Original language	English
Pages (from-to)	1997-2001
Number of pages	5
Journal	European Journal of Inorganic Chemistry
Issue number	12
DOIs	https://doi.org/10.1002/ejic.201300115
Publication status	Published - Apr 2013

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title = "Dichotomy between palladium(II)-tin(II) and palladium(0)-tin(IV) in complexes of a Sn,As-based chelate ligand",

abstract = "A dinuclear Pd-Sn bonded complex is reported, in which the interaction of the formally tin(II)-based ligand, [2-MeBrSnC6F4AsPh 2]-, with palladium appears to be best described as PdI-SnIII or Pd0-SnIV.",

keywords = "Arsenic, Moessbauer spectroscopy, Oxidation states, Palladium, Tin",

author = "Nedaossadat Mirzadeh and Martin Bennett and J{\"o}rg Wagler and Erik W{\"a}chtler and Birgit Gerke and Rainer P{\"o}ttgen and Suresh Bhargava",

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AU - Mirzadeh, Nedaossadat

AU - Bennett, Martin

AU - Wagler, Jörg

AU - Wächtler, Erik

AU - Gerke, Birgit

AU - Pöttgen, Rainer

AU - Bhargava, Suresh

PY - 2013/4

Y1 - 2013/4

N2 - A dinuclear Pd-Sn bonded complex is reported, in which the interaction of the formally tin(II)-based ligand, [2-MeBrSnC6F4AsPh 2]-, with palladium appears to be best described as PdI-SnIII or Pd0-SnIV.

AB - A dinuclear Pd-Sn bonded complex is reported, in which the interaction of the formally tin(II)-based ligand, [2-MeBrSnC6F4AsPh 2]-, with palladium appears to be best described as PdI-SnIII or Pd0-SnIV.

KW - Arsenic

KW - Moessbauer spectroscopy

KW - Oxidation states

KW - Palladium

KW - Tin

UR - http://www.scopus.com/inward/record.url?scp=84876271323&partnerID=8YFLogxK

U2 - 10.1002/ejic.201300115

DO - 10.1002/ejic.201300115

M3 - Article

SN - 1434-1948

SP - 1997

EP - 2001

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 12

ER -

Dichotomy between palladium(II)-tin(II) and palladium(0)-tin(IV) in complexes of a Sn,As-based chelate ligand

Abstract

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