Diffusion-controlled chronoamperometry at a disk electrode

Peter J. Mahon, Keith B. Oldham

    Research output: Contribution to journalArticlepeer-review

    21 Citations (Scopus)

    Abstract

    An accurate formula exists for describing the decay of the current following the imposition of extreme concentration polarization on a disk electrode under diffusion-controlled conditions. It has been amply validated by diverse simulations and is presented here in a more compact form than hitherto. The formula finds application beyond the realm of potential-step chronoamperometry.

    Original languageEnglish
    Pages (from-to)6100-6101
    Number of pages2
    JournalAnalytical Chemistry
    Volume77
    Issue number18
    DOIs
    Publication statusPublished - 15 Sept 2005

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