TY - JOUR
T1 - Diisopropylaminomethylidyne complexes of iron, chromium, molybdenum and tungsten
AU - Anderson, Stephen
AU - Hill, Anthony F.
PY - 1990/8/11
Y1 - 1990/8/11
N2 - Treatment of [M(CO)n] (n = 6, M = Cr, Mo, W; n = 5, M = Fe) successively with LiNiPr2, (CF3CO)2O, and PPh3 leads to the thermally stable diisopropylaminomethylidyne complexes [M(CNiPr2)(O2CCF3)(CO)3(PPh3)] (M = Cr, Mo, W) and [Fe(CNiPr2)(O2CCF3)(CO)2(PPh3)] in high yield. The latter is the first neutral mononuclear carbyne complex of iron.
AB - Treatment of [M(CO)n] (n = 6, M = Cr, Mo, W; n = 5, M = Fe) successively with LiNiPr2, (CF3CO)2O, and PPh3 leads to the thermally stable diisopropylaminomethylidyne complexes [M(CNiPr2)(O2CCF3)(CO)3(PPh3)] (M = Cr, Mo, W) and [Fe(CNiPr2)(O2CCF3)(CO)2(PPh3)] in high yield. The latter is the first neutral mononuclear carbyne complex of iron.
UR - http://www.scopus.com/inward/record.url?scp=0011588153&partnerID=8YFLogxK
U2 - 10.1016/0022-328X(90)87274-H
DO - 10.1016/0022-328X(90)87274-H
M3 - Article
AN - SCOPUS:0011588153
SN - 0022-328X
VL - 394
SP - c24-c26
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1-3
ER -