Diisopropylaminomethylidyne complexes of iron, chromium, molybdenum and tungsten

Stephen Anderson; Anthony F. Hill

doi:10.1016/0022-328X(90)87274-H

Diisopropylaminomethylidyne complexes of iron, chromium, molybdenum and tungsten

Stephen Anderson^*, Anthony F. Hill

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Treatment of [M(CO)_n] (n = 6, M = Cr, Mo, W; n = 5, M = Fe) successively with LiNⁱPr₂, (CF₃CO)₂O, and PPh₃ leads to the thermally stable diisopropylaminomethylidyne complexes [M(CNⁱPr₂)(O₂CCF₃)(CO)₃(PPh₃)] (M = Cr, Mo, W) and [Fe(CNⁱPr₂)(O₂CCF₃)(CO)₂(PPh₃)] in high yield. The latter is the first neutral mononuclear carbyne complex of iron.

Original language	English
Pages (from-to)	c24-c26
Journal	Journal of Organometallic Chemistry
Volume	394
Issue number	1-3
DOIs	https://doi.org/10.1016/0022-328X(90)87274-H
Publication status	Published - 11 Aug 1990
Externally published	Yes

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@article{15b91aa3a533424c8e346856e316ab82,

title = "Diisopropylaminomethylidyne complexes of iron, chromium, molybdenum and tungsten",

abstract = "Treatment of [M(CO)n] (n = 6, M = Cr, Mo, W; n = 5, M = Fe) successively with LiNiPr2, (CF3CO)2O, and PPh3 leads to the thermally stable diisopropylaminomethylidyne complexes [M(CNiPr2)(O2CCF3)(CO)3(PPh3)] (M = Cr, Mo, W) and [Fe(CNiPr2)(O2CCF3)(CO)2(PPh3)] in high yield. The latter is the first neutral mononuclear carbyne complex of iron.",

author = "Stephen Anderson and Hill, \{Anthony F.\}",

year = "1990",

month = aug,

day = "11",

doi = "10.1016/0022-328X(90)87274-H",

language = "English",

volume = "394",

pages = "c24--c26",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "1-3",

}

TY - JOUR

T1 - Diisopropylaminomethylidyne complexes of iron, chromium, molybdenum and tungsten

AU - Anderson, Stephen

AU - Hill, Anthony F.

PY - 1990/8/11

Y1 - 1990/8/11

N2 - Treatment of [M(CO)n] (n = 6, M = Cr, Mo, W; n = 5, M = Fe) successively with LiNiPr2, (CF3CO)2O, and PPh3 leads to the thermally stable diisopropylaminomethylidyne complexes [M(CNiPr2)(O2CCF3)(CO)3(PPh3)] (M = Cr, Mo, W) and [Fe(CNiPr2)(O2CCF3)(CO)2(PPh3)] in high yield. The latter is the first neutral mononuclear carbyne complex of iron.

AB - Treatment of [M(CO)n] (n = 6, M = Cr, Mo, W; n = 5, M = Fe) successively with LiNiPr2, (CF3CO)2O, and PPh3 leads to the thermally stable diisopropylaminomethylidyne complexes [M(CNiPr2)(O2CCF3)(CO)3(PPh3)] (M = Cr, Mo, W) and [Fe(CNiPr2)(O2CCF3)(CO)2(PPh3)] in high yield. The latter is the first neutral mononuclear carbyne complex of iron.

UR - https://www.scopus.com/pages/publications/0011588153

U2 - 10.1016/0022-328X(90)87274-H

DO - 10.1016/0022-328X(90)87274-H

M3 - Article

AN - SCOPUS:0011588153

SN - 0022-328X

VL - 394

SP - c24-c26

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-3

ER -

Diisopropylaminomethylidyne complexes of iron, chromium, molybdenum and tungsten

Abstract

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