Dimetallapoly-yn-diylidynes: LnM≡C−(C≡C)x−C≡MLn (x=0–4)

Anthony F. Hill; Richard A. Manzano

doi:10.1002/anie.201909550

Dimetallapoly-yn-diylidynes: L_nM≡C−(C≡C)_x−C≡ML_n (x=0–4)

Anthony F. Hill^*, Richard A. Manzano

^*Corresponding author for this work

Research School of Chemistry

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Synthetic routes to dimetallated C_x carbon wires in which two metals are separated by a linear carbon chain involving terminal metal–carbon triple bonds are described for the complexes [(Tp*)(CO)₂W≡C−(C≡C)_n−C≡W(CO)₂(Tp*)] (Tp*=hydrotris(dimethylpyrazolyl)borate) where n=1, 3 or 4, joining the previously known examples with n=0, 1 and 2 to complete the series as models for linear carbyne C_∞.

Original language	English
Pages (from-to)	15354-15357
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	58
Issue number	43
Early online date	29 Aug 2019
DOIs	https://doi.org/10.1002/anie.201909550
Publication status	Published - 21 Oct 2019

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title = "Dimetallapoly-yn-diylidynes: LnM≡C−(C≡C)x−C≡MLn (x=0–4)",

abstract = "Synthetic routes to dimetallated Cx carbon wires in which two metals are separated by a linear carbon chain involving terminal metal–carbon triple bonds are described for the complexes [(Tp*)(CO)2W≡C−(C≡C)n−C≡W(CO)2(Tp*)] (Tp*=hydrotris(dimethylpyrazolyl)borate) where n=1, 3 or 4, joining the previously known examples with n=0, 1 and 2 to complete the series as models for linear carbyne C∞.",

keywords = "bis(carbyne), carbon, carbyne, tungsten",

author = "Hill, \{Anthony F.\} and Manzano, \{Richard A.\}",

note = "Publisher Copyright: {\textcopyright} 2019 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2019",

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doi = "10.1002/anie.201909550",

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T1 - Dimetallapoly-yn-diylidynes: LnM≡C−(C≡C)x−C≡MLn (x=0–4)

AU - Hill, Anthony F.

AU - Manzano, Richard A.

PY - 2019/10/21

Y1 - 2019/10/21

N2 - Synthetic routes to dimetallated Cx carbon wires in which two metals are separated by a linear carbon chain involving terminal metal–carbon triple bonds are described for the complexes [(Tp*)(CO)2W≡C−(C≡C)n−C≡W(CO)2(Tp*)] (Tp*=hydrotris(dimethylpyrazolyl)borate) where n=1, 3 or 4, joining the previously known examples with n=0, 1 and 2 to complete the series as models for linear carbyne C∞.

AB - Synthetic routes to dimetallated Cx carbon wires in which two metals are separated by a linear carbon chain involving terminal metal–carbon triple bonds are described for the complexes [(Tp*)(CO)2W≡C−(C≡C)n−C≡W(CO)2(Tp*)] (Tp*=hydrotris(dimethylpyrazolyl)borate) where n=1, 3 or 4, joining the previously known examples with n=0, 1 and 2 to complete the series as models for linear carbyne C∞.

KW - bis(carbyne)

KW - carbon

KW - carbyne

KW - tungsten

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JO - Angewandte Chemie - International Edition

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ER -

Dimetallapoly-yn-diylidynes: L_nM≡C−(C≡C)_x−C≡ML_n (x=0–4)

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