Diphenylamino-substituted tristyryl: Vs. triphenyl isocyanurates: Improved conjugation has minimal impact on two-photon absorption

Amédée Triadon; Alphonsine Ngo Ndimba; Nicolas Richy; Anissa Amar; Abdou Boucekkine; Thierry Roisnel; Marie P. Cifuentes; Mark G. Humphrey; Mireille Blanchard-Desce; Olivier Mongin; Frédéric Paul

doi:10.1039/c8nj01904e

Diphenylamino-substituted tristyryl: Vs. triphenyl isocyanurates: Improved conjugation has minimal impact on two-photon absorption

Amédée Triadon
, Alphonsine Ngo Ndimba
, Nicolas Richy
, Anissa Amar
, Abdou Boucekkine
, Thierry Roisnel
, Marie P. Cifuentes
, Mark G. Humphrey^*
, Mireille Blanchard-Desce
, Olivier Mongin
, Frédéric Paul

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

This contribution reports the synthesis of C₈₇H₆₀N₆O₃ (3-NPh₂), the tristyryl analogue of the triphenylisocyanurate C₈₁H₅₄N₆O₃ (2-NPh₂) which was previously demonstrated to be an active two-photon absorber. Contrary to expectation, planarization and extension of the central π-system does not lead to a marked improvement of the two-photon absorption cross-section.

Original language	English
Pages (from-to)	11289-11293
Number of pages	5
Journal	New Journal of Chemistry
Volume	42
Issue number	14
DOIs	https://doi.org/10.1039/c8nj01904e
Publication status	Published - 2018

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10.1039/c8nj01904e

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Triadon, A., Ngo Ndimba, A., Richy, N., Amar, A., Boucekkine, A., Roisnel, T., Cifuentes, M. P., Humphrey, M. G., Blanchard-Desce, M., Mongin, O., & Paul, F. (2018). Diphenylamino-substituted tristyryl: Vs. triphenyl isocyanurates: Improved conjugation has minimal impact on two-photon absorption. New Journal of Chemistry, 42(14), 11289-11293. https://doi.org/10.1039/c8nj01904e

@article{56d4335b12b14f29af925c42396258fd,

title = "Diphenylamino-substituted tristyryl: Vs. triphenyl isocyanurates: Improved conjugation has minimal impact on two-photon absorption",

abstract = "This contribution reports the synthesis of C87H60N6O3 (3-NPh2), the tristyryl analogue of the triphenylisocyanurate C81H54N6O3 (2-NPh2) which was previously demonstrated to be an active two-photon absorber. Contrary to expectation, planarization and extension of the central π-system does not lead to a marked improvement of the two-photon absorption cross-section.",

author = "Am{\'e}d{\'e}e Triadon and \{Ngo Ndimba\}, Alphonsine and Nicolas Richy and Anissa Amar and Abdou Boucekkine and Thierry Roisnel and Cifuentes, \{Marie P.\} and Humphrey, \{Mark G.\} and Mireille Blanchard-Desce and Olivier Mongin and Fr{\'e}d{\'e}ric Paul",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.",

year = "2018",

doi = "10.1039/c8nj01904e",

language = "English",

volume = "42",

pages = "11289--11293",

journal = "New Journal of Chemistry",

issn = "1144-0546",

publisher = "Royal Society of Chemistry",

number = "14",

}

Triadon, A, Ngo Ndimba, A, Richy, N, Amar, A, Boucekkine, A, Roisnel, T, Cifuentes, MP, Humphrey, MG, Blanchard-Desce, M, Mongin, O & Paul, F 2018, 'Diphenylamino-substituted tristyryl: Vs. triphenyl isocyanurates: Improved conjugation has minimal impact on two-photon absorption', New Journal of Chemistry, vol. 42, no. 14, pp. 11289-11293. https://doi.org/10.1039/c8nj01904e

TY - JOUR

T1 - Diphenylamino-substituted tristyryl

T2 - Vs. triphenyl isocyanurates: Improved conjugation has minimal impact on two-photon absorption

AU - Triadon, Amédée

AU - Ngo Ndimba, Alphonsine

AU - Richy, Nicolas

AU - Amar, Anissa

AU - Boucekkine, Abdou

AU - Roisnel, Thierry

AU - Cifuentes, Marie P.

AU - Humphrey, Mark G.

AU - Blanchard-Desce, Mireille

AU - Mongin, Olivier

AU - Paul, Frédéric

PY - 2018

Y1 - 2018

N2 - This contribution reports the synthesis of C87H60N6O3 (3-NPh2), the tristyryl analogue of the triphenylisocyanurate C81H54N6O3 (2-NPh2) which was previously demonstrated to be an active two-photon absorber. Contrary to expectation, planarization and extension of the central π-system does not lead to a marked improvement of the two-photon absorption cross-section.

AB - This contribution reports the synthesis of C87H60N6O3 (3-NPh2), the tristyryl analogue of the triphenylisocyanurate C81H54N6O3 (2-NPh2) which was previously demonstrated to be an active two-photon absorber. Contrary to expectation, planarization and extension of the central π-system does not lead to a marked improvement of the two-photon absorption cross-section.

UR - https://www.scopus.com/pages/publications/85049754889

U2 - 10.1039/c8nj01904e

DO - 10.1039/c8nj01904e

M3 - Article

SN - 1144-0546

VL - 42

SP - 11289

EP - 11293

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 14

ER -

Diphenylamino-substituted tristyryl: Vs. triphenyl isocyanurates: Improved conjugation has minimal impact on two-photon absorption

Abstract

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