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Dispersion of the complex cubic nonlinearity in two-photon absorbing organic and organometallic chromophores

  • Marek Samoc*
  • , Anna Samoc
  • , Gulliver T. Dalton
  • , Marie P. Cifuentes
  • , Mark G. Humphrey
  • , Paul A. Fleitz
  • *Corresponding author for this work

    Research output: Chapter in Book/Report/Conference proceedingConference Paperpeer-review

    4 Citations (Scopus)

    Abstract

    There is much interest in nonlinear absorbing chromophores for applications in photonics, nanophotonics and biophotonics. We have performed studies of dispersion of the nonlinear absorption cross sections and the refractive nonlinearities of organic and organometallic nonlinear chromophores using the technique of Z-scan, with a tunable amplified femtosecond laser system. Z-scan is less sensitive than the popular technique of two-photon induced fluorescence but has advantages of being suitable for non-fluorescent substances and providing information on both absorptive and refractive nonlinearities. We have analysed the experimental results in terms of simple models and using the Kramers-Kronig transformation as shown in this paper for Coumarine 307 and an organometallic dendrimer. The dispersion curves are often dominated by two-photon resonances but inclusion of other nonlinear mechanisms seems to be necessary for better understanding of their features.

    Original languageEnglish
    Title of host publicationPhotonics
    Subtitle of host publicationDesign, Technology, and Packaging III
    DOIs
    Publication statusPublished - 2008
    EventPhotonics: Design, Technology, and Packaging III - Canberra, Australia
    Duration: 5 Dec 20077 Dec 2007

    Publication series

    NameProceedings of SPIE - The International Society for Optical Engineering
    Volume6801
    ISSN (Print)0277-786X

    Conference

    ConferencePhotonics: Design, Technology, and Packaging III
    Country/TerritoryAustralia
    CityCanberra
    Period5/12/077/12/07

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