Dispersion of the third-order nonlinear optical properties of an organometallic dendrimer

Clem E. Powell; Joseph P. Morrall; Simone A. Ward; Marie P. Cifuentes; Eleni G.A. Notaras; Marek Samoc; Mark G. Humphrey

doi:10.1021/ja048608l

Dispersion of the third-order nonlinear optical properties of an organometallic dendrimer

Clem E. Powell, Joseph P. Morrall, Simone A. Ward, Marie P. Cifuentes, Eleni G.A. Notaras, Marek Samoc^*, Mark G. Humphrey

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

119 Citations (Scopus)

Abstract

The dispersion of cubic nonlinearity in the organometallic dendrimer 1,3,5-(3,5-{trans-[(dppe)₂(4-O₂NC₆H₄C_≡C)RuC_≡C]}₂C₆H₃C_≡CC₆H₄-4-C_≡C)₃C₆H₃ can be understood in terms of an interplay of two-photon absorption and absorption saturation. Simple dispersion relations reproduce the behavior of both the real and imaginary components of the hyperpolarizability.

Original language	English
Pages (from-to)	12234-12235
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	126
Issue number	39
DOIs	https://doi.org/10.1021/ja048608l
Publication status	Published - 6 Oct 2004

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abstract = "The dispersion of cubic nonlinearity in the organometallic dendrimer 1,3,5-(3,5-{trans-[(dppe)2(4-O2NC6H4C≡C)RuC≡C]}2C6H3C≡CC6H4-4-C≡C)3C6H3 can be understood in terms of an interplay of two-photon absorption and absorption saturation. Simple dispersion relations reproduce the behavior of both the real and imaginary components of the hyperpolarizability.",

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AU - Powell, Clem E.

AU - Morrall, Joseph P.

AU - Ward, Simone A.

AU - Cifuentes, Marie P.

AU - Notaras, Eleni G.A.

AU - Samoc, Marek

AU - Humphrey, Mark G.

PY - 2004/10/6

Y1 - 2004/10/6

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AB - The dispersion of cubic nonlinearity in the organometallic dendrimer 1,3,5-(3,5-{trans-[(dppe)2(4-O2NC6H4C≡C)RuC≡C]}2C6H3C≡CC6H4-4-C≡C)3C6H3 can be understood in terms of an interplay of two-photon absorption and absorption saturation. Simple dispersion relations reproduce the behavior of both the real and imaginary components of the hyperpolarizability.

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U2 - 10.1021/ja048608l

DO - 10.1021/ja048608l

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 39

ER -

Dispersion of the third-order nonlinear optical properties of an organometallic dendrimer

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