Dispersion of the third-order nonlinear optical properties of an organometallic dendrimer

Clem E. Powell; Joseph P. Morrall; Simone A. Ward; Marie P. Cifuentes; Eleni G.A. Notaras; Marek Samoc; Mark G. Humphrey

doi:10.1021/ja048608l

Dispersion of the third-order nonlinear optical properties of an organometallic dendrimer

Clem E. Powell
, Joseph P. Morrall
, Simone A. Ward
, Marie P. Cifuentes
, Eleni G.A. Notaras
, Marek Samoc^*
, Mark G. Humphrey

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

127 Citations (Scopus)

Abstract

The dispersion of cubic nonlinearity in the organometallic dendrimer 1,3,5-(3,5-{trans-[(dppe)₂(4-O₂NC₆H₄C_≡C)RuC_≡C]}₂C₆H₃C_≡CC₆H₄-4-C_≡C)₃C₆H₃ can be understood in terms of an interplay of two-photon absorption and absorption saturation. Simple dispersion relations reproduce the behavior of both the real and imaginary components of the hyperpolarizability.

Original language	English
Pages (from-to)	12234-12235
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	126
Issue number	39
DOIs	https://doi.org/10.1021/ja048608l
Publication status	Published - 6 Oct 2004

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title = "Dispersion of the third-order nonlinear optical properties of an organometallic dendrimer",

abstract = "The dispersion of cubic nonlinearity in the organometallic dendrimer 1,3,5-(3,5-\{trans-[(dppe)2(4-O2NC6H4C≡C)RuC≡C]\}2C6H3C≡CC6H4-4-C≡C)3C6H3 can be understood in terms of an interplay of two-photon absorption and absorption saturation. Simple dispersion relations reproduce the behavior of both the real and imaginary components of the hyperpolarizability.",

author = "Powell, \{Clem E.\} and Morrall, \{Joseph P.\} and Ward, \{Simone A.\} and Cifuentes, \{Marie P.\} and Notaras, \{Eleni G.A.\} and Marek Samoc and Humphrey, \{Mark G.\}",

year = "2004",

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doi = "10.1021/ja048608l",

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T1 - Dispersion of the third-order nonlinear optical properties of an organometallic dendrimer

AU - Powell, Clem E.

AU - Morrall, Joseph P.

AU - Ward, Simone A.

AU - Cifuentes, Marie P.

AU - Notaras, Eleni G.A.

AU - Samoc, Marek

AU - Humphrey, Mark G.

PY - 2004/10/6

Y1 - 2004/10/6

N2 - The dispersion of cubic nonlinearity in the organometallic dendrimer 1,3,5-(3,5-{trans-[(dppe)2(4-O2NC6H4C≡C)RuC≡C]}2C6H3C≡CC6H4-4-C≡C)3C6H3 can be understood in terms of an interplay of two-photon absorption and absorption saturation. Simple dispersion relations reproduce the behavior of both the real and imaginary components of the hyperpolarizability.

AB - The dispersion of cubic nonlinearity in the organometallic dendrimer 1,3,5-(3,5-{trans-[(dppe)2(4-O2NC6H4C≡C)RuC≡C]}2C6H3C≡CC6H4-4-C≡C)3C6H3 can be understood in terms of an interplay of two-photon absorption and absorption saturation. Simple dispersion relations reproduce the behavior of both the real and imaginary components of the hyperpolarizability.

UR - https://www.scopus.com/pages/publications/4644344332

U2 - 10.1021/ja048608l

DO - 10.1021/ja048608l

M3 - Article

SN - 0002-7863

VL - 126

SP - 12234

EP - 12235

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 39

ER -

Dispersion of the third-order nonlinear optical properties of an organometallic dendrimer

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