TY - JOUR
T1 - Diyne coordination chemistry
T2 - Reactions of [RuClH(CO)(PPh3)3] with diphenylbutadiyne and bis(phenylethynyl)mercury
AU - Hill, Anthony F.
AU - Melling, Richard P.
PY - 1990/10/9
Y1 - 1990/10/9
N2 - The reaction of the hydridometal complex [RuClH(CO)(PPh3)3] with 1,4-diphenyl-butadi-1,3-yne has been investigated and found to proceed with monoinsertion to give a coordinatively unsaturated σ-vinyl complex [Ru-{C(CCPh)CHPh} Cl(CO)(PPh3)2], which is also the major product of the reaction of [RuClH(CO) (PPh3)3] with [Hg(CCPh)2].
AB - The reaction of the hydridometal complex [RuClH(CO)(PPh3)3] with 1,4-diphenyl-butadi-1,3-yne has been investigated and found to proceed with monoinsertion to give a coordinatively unsaturated σ-vinyl complex [Ru-{C(CCPh)CHPh} Cl(CO)(PPh3)2], which is also the major product of the reaction of [RuClH(CO) (PPh3)3] with [Hg(CCPh)2].
UR - http://www.scopus.com/inward/record.url?scp=0010955905&partnerID=8YFLogxK
U2 - 10.1016/0022-328X(90)85205-D
DO - 10.1016/0022-328X(90)85205-D
M3 - Article
AN - SCOPUS:0010955905
SN - 0022-328X
VL - 396
SP - C22-C24
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1
ER -