Dodecanuclear-ellipse and decanuclear-wheel nickel(II) thiolato clusters with efficient femtosecond nonlinear absorption

Chi Zhang; Tsuyoshi Matsumoto; Marek Samoc; Simon Petrie; Suei Meng; T. Christopher Corkery; Robert Stranger; Jinfang Zhang; Mark G. Humphrey; Kazuyuki Tatsumi

doi:10.1002/anie.200907074

Dodecanuclear-ellipse and decanuclear-wheel nickel(II) thiolato clusters with efficient femtosecond nonlinear absorption

Chi Zhang^*, Tsuyoshi Matsumoto, Marek Samoc, Simon Petrie, Suei Meng, T. Christopher Corkery, Robert Stranger, Jinfang Zhang, Mark G. Humphrey, Kazuyuki Tatsumi

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

54 Citations (Scopus)

Abstract

(Figure Presented) Crowned with success: Stepwise coordination of two kinds of thiolate ligands to a nickel (II) center affords a dodecanuclear ellipse (see structure) and two decanuclear wheel-like Ni^II-thiolato clusters. The wavelength-dependent nonlinear optical behavior of these tiara-like compounds was investigated and supported by theoretical studies. The results suggest that Ni-S π bonds play a crucial role.

Original language	English
Pages (from-to)	4209-4212
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	25
DOIs	https://doi.org/10.1002/anie.200907074
Publication status	Published - 7 Jun 2010

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Zhang, C., Matsumoto, T., Samoc, M., Petrie, S., Meng, S., Christopher Corkery, T., Stranger, R., Zhang, J., Humphrey, M. G., & Tatsumi, K. (2010). Dodecanuclear-ellipse and decanuclear-wheel nickel(II) thiolato clusters with efficient femtosecond nonlinear absorption. Angewandte Chemie - International Edition, 49(25), 4209-4212. https://doi.org/10.1002/anie.200907074

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title = "Dodecanuclear-ellipse and decanuclear-wheel nickel(II) thiolato clusters with efficient femtosecond nonlinear absorption",

abstract = "(Figure Presented) Crowned with success: Stepwise coordination of two kinds of thiolate ligands to a nickel (II) center affords a dodecanuclear ellipse (see structure) and two decanuclear wheel-like NiII-thiolato clusters. The wavelength-dependent nonlinear optical behavior of these tiara-like compounds was investigated and supported by theoretical studies. The results suggest that Ni-S π bonds play a crucial role.",

keywords = "Cluster compounds, Nonlinear optics, Td-dft calculations, Thiolate ligands, Tiara structures",

author = "Chi Zhang and Tsuyoshi Matsumoto and Marek Samoc and Simon Petrie and Suei Meng and {Christopher Corkery}, T. and Robert Stranger and Jinfang Zhang and Humphrey, {Mark G.} and Kazuyuki Tatsumi",

year = "2010",

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doi = "10.1002/anie.200907074",

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volume = "49",

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Zhang, C, Matsumoto, T, Samoc, M, Petrie, S, Meng, S, Christopher Corkery, T, Stranger, R, Zhang, J, Humphrey, MG & Tatsumi, K 2010, 'Dodecanuclear-ellipse and decanuclear-wheel nickel(II) thiolato clusters with efficient femtosecond nonlinear absorption', Angewandte Chemie - International Edition, vol. 49, no. 25, pp. 4209-4212. https://doi.org/10.1002/anie.200907074

TY - JOUR

T1 - Dodecanuclear-ellipse and decanuclear-wheel nickel(II) thiolato clusters with efficient femtosecond nonlinear absorption

AU - Zhang, Chi

AU - Matsumoto, Tsuyoshi

AU - Samoc, Marek

AU - Petrie, Simon

AU - Meng, Suei

AU - Christopher Corkery, T.

AU - Stranger, Robert

AU - Zhang, Jinfang

AU - Humphrey, Mark G.

AU - Tatsumi, Kazuyuki

PY - 2010/6/7

Y1 - 2010/6/7

N2 - (Figure Presented) Crowned with success: Stepwise coordination of two kinds of thiolate ligands to a nickel (II) center affords a dodecanuclear ellipse (see structure) and two decanuclear wheel-like NiII-thiolato clusters. The wavelength-dependent nonlinear optical behavior of these tiara-like compounds was investigated and supported by theoretical studies. The results suggest that Ni-S π bonds play a crucial role.

AB - (Figure Presented) Crowned with success: Stepwise coordination of two kinds of thiolate ligands to a nickel (II) center affords a dodecanuclear ellipse (see structure) and two decanuclear wheel-like NiII-thiolato clusters. The wavelength-dependent nonlinear optical behavior of these tiara-like compounds was investigated and supported by theoretical studies. The results suggest that Ni-S π bonds play a crucial role.

KW - Cluster compounds

KW - Nonlinear optics

KW - Td-dft calculations

KW - Thiolate ligands

KW - Tiara structures

UR - http://www.scopus.com/inward/record.url?scp=77953489542&partnerID=8YFLogxK

U2 - 10.1002/anie.200907074

DO - 10.1002/anie.200907074

M3 - Article

SN - 1433-7851

VL - 49

SP - 4209

EP - 4212

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 25

ER -

Dodecanuclear-ellipse and decanuclear-wheel nickel(II) thiolato clusters with efficient femtosecond nonlinear absorption

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