TY - JOUR
T1 - Domino pericyclic reactions of acyclic conjugated (E,Z,E,E)-tetraenes
AU - Skropeta, Danielle
AU - Rickards, Rodney W.
PY - 2007/4/30
Y1 - 2007/4/30
N2 - Acyclic conjugated (E,Z,E,E)-tetraenes, upon thermolysis, undergo a domino pericyclic process involving 6π electrocyclisation of the (E,Z,E)-triene moiety to give the corresponding cis-disubstituted 5-vinyl-1,3-cyclohexadienes, followed by an intramolecular Diels-Alder reaction with the vinyl side chain to give tricyclo[3.2.1.02,7]oct-3-enes.
AB - Acyclic conjugated (E,Z,E,E)-tetraenes, upon thermolysis, undergo a domino pericyclic process involving 6π electrocyclisation of the (E,Z,E)-triene moiety to give the corresponding cis-disubstituted 5-vinyl-1,3-cyclohexadienes, followed by an intramolecular Diels-Alder reaction with the vinyl side chain to give tricyclo[3.2.1.02,7]oct-3-enes.
KW - Electrocyclic reaction
KW - Intramolecular Diels-Alder reaction
KW - Polyenes
KW - Tetraenes
UR - http://www.scopus.com/inward/record.url?scp=34047183626&partnerID=8YFLogxK
U2 - 10.1016/j.tetlet.2007.03.011
DO - 10.1016/j.tetlet.2007.03.011
M3 - Article
SN - 0040-4039
VL - 48
SP - 3281
EP - 3284
JO - Tetrahedron Letters
JF - Tetrahedron Letters
IS - 18
ER -