Electrochemical switching of the cubic nonlinear optical properties of an aryldiethynyl-linked heterobimetallic complex between three distinct states

Marek Samoc; Nicolas Gauthier; Marie P. Cifuentes; Frédéric Paul; Claude Lapinte; Mark G. Humphrey

doi:10.1002/anie.200602684

Electrochemical switching of the cubic nonlinear optical properties of an aryldiethynyl-linked heterobimetallic complex between three distinct states

Marek Samoc^*, Nicolas Gauthier, Marie P. Cifuentes, Frédéric Paul, Claude Lapinte, Mark G. Humphrey

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

167 Citations (Scopus)

Abstract

(Chemical Equation Presented) Successive oxidation processes in a heterobimetallic iron-ruthenium complex (see picture) "switch" the optical transitions at long wavelengths, and these linear electrochromic effects are accompanied by changes in the nonlinear optical properties of the complex.

Original language	English
Pages (from-to)	7376-7379
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	44
DOIs	https://doi.org/10.1002/anie.200602684
Publication status	Published - 13 Nov 2006

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10.1002/anie.200602684

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title = "Electrochemical switching of the cubic nonlinear optical properties of an aryldiethynyl-linked heterobimetallic complex between three distinct states",

abstract = "(Chemical Equation Presented) Successive oxidation processes in a heterobimetallic iron-ruthenium complex (see picture) {"}switch{"} the optical transitions at long wavelengths, and these linear electrochromic effects are accompanied by changes in the nonlinear optical properties of the complex.",

keywords = "Alkynyl ligands, Electrochemistry, Molecular switches, Nonlinear optics",

author = "Marek Samoc and Nicolas Gauthier and Cifuentes, \{Marie P.\} and Fr{\'e}d{\'e}ric Paul and Claude Lapinte and Humphrey, \{Mark G.\}",

year = "2006",

month = nov,

day = "13",

doi = "10.1002/anie.200602684",

language = "English",

volume = "45",

pages = "7376--7379",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley \& Sons Ltd.",

number = "44",

}

Electrochemical switching of the cubic nonlinear optical properties of an aryldiethynyl-linked heterobimetallic complex between three distinct states. / Samoc, Marek; Gauthier, Nicolas; Cifuentes, Marie P. et al.
In: Angewandte Chemie - International Edition, Vol. 45, No. 44, 13.11.2006, p. 7376-7379.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Electrochemical switching of the cubic nonlinear optical properties of an aryldiethynyl-linked heterobimetallic complex between three distinct states

AU - Samoc, Marek

AU - Gauthier, Nicolas

AU - Cifuentes, Marie P.

AU - Paul, Frédéric

AU - Lapinte, Claude

AU - Humphrey, Mark G.

PY - 2006/11/13

Y1 - 2006/11/13

N2 - (Chemical Equation Presented) Successive oxidation processes in a heterobimetallic iron-ruthenium complex (see picture) "switch" the optical transitions at long wavelengths, and these linear electrochromic effects are accompanied by changes in the nonlinear optical properties of the complex.

AB - (Chemical Equation Presented) Successive oxidation processes in a heterobimetallic iron-ruthenium complex (see picture) "switch" the optical transitions at long wavelengths, and these linear electrochromic effects are accompanied by changes in the nonlinear optical properties of the complex.

KW - Alkynyl ligands

KW - Electrochemistry

KW - Molecular switches

KW - Nonlinear optics

UR - https://www.scopus.com/pages/publications/33751210317

U2 - 10.1002/anie.200602684

DO - 10.1002/anie.200602684

M3 - Article

SN - 1433-7851

VL - 45

SP - 7376

EP - 7379

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 44

ER -

Electrochemical switching of the cubic nonlinear optical properties of an aryldiethynyl-linked heterobimetallic complex between three distinct states

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