Enhanced two-photon absorption cross-sections of zinc(II) tetraphenylporphyrins peripherally substituted with d6-metal alkynyl complexes

Samuel Drouet; Areej Merhi; Guillaume Grelaud; Marie P. Cifuentes; Mark G. Humphrey; Katarzyna Matczyszyn; Marek Samoc; Loïc Toupet; Christine O. Paul-Roth; Frédéric Paul

doi:10.1039/c2nj40589j

Enhanced two-photon absorption cross-sections of zinc(II) tetraphenylporphyrins peripherally substituted with d⁶-metal alkynyl complexes

Samuel Drouet, Areej Merhi, Guillaume Grelaud, Marie P. Cifuentes, Mark G. Humphrey^*, Katarzyna Matczyszyn, Marek Samoc, Loïc Toupet, Christine O. Paul-Roth, Frédéric Paul

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

The syntheses of new Zn(ii) tetraphenylporphyrin (ZnTPP) derivatives functionalized with electron-rich d⁶-transition metal alkynyl complexes at their periphery are reported. Z-scan measurements reveal remarkably large effective two-photon absorption (TPA) cross-sections in the visible range for these compounds.

Original language	English
Pages (from-to)	2192-2195
Number of pages	4
Journal	New Journal of Chemistry
Volume	36
Issue number	11
DOIs	https://doi.org/10.1039/c2nj40589j
Publication status	Published - Nov 2012

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title = "Enhanced two-photon absorption cross-sections of zinc(II) tetraphenylporphyrins peripherally substituted with d6-metal alkynyl complexes",

abstract = "The syntheses of new Zn(ii) tetraphenylporphyrin (ZnTPP) derivatives functionalized with electron-rich d6-transition metal alkynyl complexes at their periphery are reported. Z-scan measurements reveal remarkably large effective two-photon absorption (TPA) cross-sections in the visible range for these compounds.",

author = "Samuel Drouet and Areej Merhi and Guillaume Grelaud and Cifuentes, {Marie P.} and Humphrey, {Mark G.} and Katarzyna Matczyszyn and Marek Samoc and Lo{\"i}c Toupet and Paul-Roth, {Christine O.} and Fr{\'e}d{\'e}ric Paul",

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month = nov,

doi = "10.1039/c2nj40589j",

language = "English",

volume = "36",

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publisher = "Royal Society of Chemistry",

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T1 - Enhanced two-photon absorption cross-sections of zinc(II) tetraphenylporphyrins peripherally substituted with d6-metal alkynyl complexes

AU - Drouet, Samuel

AU - Merhi, Areej

AU - Grelaud, Guillaume

AU - Cifuentes, Marie P.

AU - Humphrey, Mark G.

AU - Matczyszyn, Katarzyna

AU - Samoc, Marek

AU - Toupet, Loïc

AU - Paul-Roth, Christine O.

AU - Paul, Frédéric

PY - 2012/11

Y1 - 2012/11

N2 - The syntheses of new Zn(ii) tetraphenylporphyrin (ZnTPP) derivatives functionalized with electron-rich d6-transition metal alkynyl complexes at their periphery are reported. Z-scan measurements reveal remarkably large effective two-photon absorption (TPA) cross-sections in the visible range for these compounds.

AB - The syntheses of new Zn(ii) tetraphenylporphyrin (ZnTPP) derivatives functionalized with electron-rich d6-transition metal alkynyl complexes at their periphery are reported. Z-scan measurements reveal remarkably large effective two-photon absorption (TPA) cross-sections in the visible range for these compounds.

UR - http://www.scopus.com/inward/record.url?scp=84867542027&partnerID=8YFLogxK

U2 - 10.1039/c2nj40589j

DO - 10.1039/c2nj40589j

M3 - Article

SN - 1144-0546

VL - 36

SP - 2192

EP - 2195

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 11

ER -

Enhanced two-photon absorption cross-sections of zinc(II) tetraphenylporphyrins peripherally substituted with d⁶-metal alkynyl complexes

Abstract

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