Evidence for rhenium enrichment in the mantle wedge from submarine arc-like volcanic glasses (Papua New Guinea)

The low Re abundance in arc-type volcanic rocks characterized by high ¹⁸⁷Os/¹⁸⁸Os ratios is an unsolved puzzle of the ¹⁸⁷Re-¹⁸⁷OS isotope system, leaving a significant gap in our understanding of the evolution of the upper mantle-continental crust system. Here we report new observations of high Re concentrations in fresh, submarine-erupted-i.e., relatively undegassed-island arc-like volcanic glasses dredged from the eastern Manus Basin, offshore Papua New Guinea. These observations, together with previously published reports of high Re concentrations in arc-type melt inclusions, indicate that undegassed arc-type volcanic rocks and the mantle wedge are enriched in Re. Consequently, the Re concentration in the continental crust is likely to be as high as ∼2 ppb, much higher than previously estimated. The low Re concentrations in subaerial arc-type volcanic rocks are probably due to Re loss during magma degassing.