Exceptionally large two- and three-photon absorption cross-sections by OPV organometalation

Beibei Gao; Leszek M. Mazur; Mahbod Morshedi; Adam Barlow; Huan Wang; Cristóbal Quintana; Chi Zhang; Marek Samoc; Marie P. Cifuentes; Mark G. Humphrey

doi:10.1039/c6cc02560a

Exceptionally large two- and three-photon absorption cross-sections by OPV organometalation

Beibei Gao
, Leszek M. Mazur
, Mahbod Morshedi
, Adam Barlow
, Huan Wang
, Cristóbal Quintana
, Chi Zhang
, Marek Samoc
, Marie P. Cifuentes
, Mark G. Humphrey^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Oligo(p-phenylenevinylene)s (OPVs) containing up to 8 PV units and end-functionalized by ruthenium alkynyl groups have been prepared and their nonlinear absorption properties assessed using the Z-scan technique and employing low repetition rate femtosecond pulses. Exceptionally large two-photon absorption (ca. 12500 GM at 725 nm) and three-photon absorption cross sections (ca. 1.6 × 10^-76 cm⁶ s² at 1100 nm) are found for the 8PV-containing example, highlighting the potential of an "organometalation" approach to NLO-efficient organic materials.

Original language	English
Pages (from-to)	8301-8304
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	53
DOIs	https://doi.org/10.1039/c6cc02560a
Publication status	Published - 2016

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10.1039/c6cc02560a

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title = "Exceptionally large two- and three-photon absorption cross-sections by OPV organometalation",

abstract = "Oligo(p-phenylenevinylene)s (OPVs) containing up to 8 PV units and end-functionalized by ruthenium alkynyl groups have been prepared and their nonlinear absorption properties assessed using the Z-scan technique and employing low repetition rate femtosecond pulses. Exceptionally large two-photon absorption (ca. 12500 GM at 725 nm) and three-photon absorption cross sections (ca. 1.6 × 10-76 cm6 s2 at 1100 nm) are found for the 8PV-containing example, highlighting the potential of an {"}organometalation{"} approach to NLO-efficient organic materials.",

author = "Beibei Gao and Mazur, \{Leszek M.\} and Mahbod Morshedi and Adam Barlow and Huan Wang and Crist{\'o}bal Quintana and Chi Zhang and Marek Samoc and Cifuentes, \{Marie P.\} and Humphrey, \{Mark G.\}",

note = "Publisher Copyright: This journal is {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6cc02560a",

language = "English",

volume = "52",

pages = "8301--8304",

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T1 - Exceptionally large two- and three-photon absorption cross-sections by OPV organometalation

AU - Gao, Beibei

AU - Mazur, Leszek M.

AU - Morshedi, Mahbod

AU - Barlow, Adam

AU - Wang, Huan

AU - Quintana, Cristóbal

AU - Zhang, Chi

AU - Samoc, Marek

AU - Cifuentes, Marie P.

AU - Humphrey, Mark G.

PY - 2016

Y1 - 2016

N2 - Oligo(p-phenylenevinylene)s (OPVs) containing up to 8 PV units and end-functionalized by ruthenium alkynyl groups have been prepared and their nonlinear absorption properties assessed using the Z-scan technique and employing low repetition rate femtosecond pulses. Exceptionally large two-photon absorption (ca. 12500 GM at 725 nm) and three-photon absorption cross sections (ca. 1.6 × 10-76 cm6 s2 at 1100 nm) are found for the 8PV-containing example, highlighting the potential of an "organometalation" approach to NLO-efficient organic materials.

AB - Oligo(p-phenylenevinylene)s (OPVs) containing up to 8 PV units and end-functionalized by ruthenium alkynyl groups have been prepared and their nonlinear absorption properties assessed using the Z-scan technique and employing low repetition rate femtosecond pulses. Exceptionally large two-photon absorption (ca. 12500 GM at 725 nm) and three-photon absorption cross sections (ca. 1.6 × 10-76 cm6 s2 at 1100 nm) are found for the 8PV-containing example, highlighting the potential of an "organometalation" approach to NLO-efficient organic materials.

UR - https://www.scopus.com/pages/publications/84976338457

U2 - 10.1039/c6cc02560a

DO - 10.1039/c6cc02560a

M3 - Article

SN - 1359-7345

VL - 52

SP - 8301

EP - 8304

JO - Chemical Communications

JF - Chemical Communications

IS - 53

ER -

Exceptionally large two- and three-photon absorption cross-sections by OPV organometalation

Abstract

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