Exploiting the Anders-Gaßner variant on the Wittig reaction: new methodology for the synthesis of 3,3-dimethylacroyl enol esters

Brett D. Schwartz; Craig M. Williams; Ernst Anders; Paul V. Bernhardt

doi:10.1016/j.tet.2008.04.068

Exploiting the Anders-Gaßner variant on the Wittig reaction: new methodology for the synthesis of 3,3-dimethylacroyl enol esters

Brett D. Schwartz, Craig M. Williams^*, Ernst Anders, Paul V. Bernhardt

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

A one pot synthesis of the 3,3-dimethylacroyl enol ester function found in the vibsane type diterpenes has been developed based on the Anders-Gaßner variant of the Wittig reaction (AGW reaction). This method uses easily accessible acyloxyalkylidene phosphoranes and a variety of aldehydes.

Original language	English
Pages (from-to)	6482-6487
Number of pages	6
Journal	Tetrahedron
Volume	64
Issue number	27
DOIs	https://doi.org/10.1016/j.tet.2008.04.068
Publication status	Published - 30 Jun 2008
Externally published	Yes

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10.1016/j.tet.2008.04.068

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title = "Exploiting the Anders-Ga{\ss}ner variant on the Wittig reaction: new methodology for the synthesis of 3,3-dimethylacroyl enol esters",

abstract = "A one pot synthesis of the 3,3-dimethylacroyl enol ester function found in the vibsane type diterpenes has been developed based on the Anders-Ga{\ss}ner variant of the Wittig reaction (AGW reaction). This method uses easily accessible acyloxyalkylidene phosphoranes and a variety of aldehydes.",

author = "Schwartz, \{Brett D.\} and Williams, \{Craig M.\} and Ernst Anders and Bernhardt, \{Paul V.\}",

year = "2008",

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doi = "10.1016/j.tet.2008.04.068",

language = "English",

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journal = "Tetrahedron",

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T2 - new methodology for the synthesis of 3,3-dimethylacroyl enol esters

AU - Schwartz, Brett D.

AU - Williams, Craig M.

AU - Anders, Ernst

AU - Bernhardt, Paul V.

PY - 2008/6/30

Y1 - 2008/6/30

N2 - A one pot synthesis of the 3,3-dimethylacroyl enol ester function found in the vibsane type diterpenes has been developed based on the Anders-Gaßner variant of the Wittig reaction (AGW reaction). This method uses easily accessible acyloxyalkylidene phosphoranes and a variety of aldehydes.

AB - A one pot synthesis of the 3,3-dimethylacroyl enol ester function found in the vibsane type diterpenes has been developed based on the Anders-Gaßner variant of the Wittig reaction (AGW reaction). This method uses easily accessible acyloxyalkylidene phosphoranes and a variety of aldehydes.

UR - https://www.scopus.com/pages/publications/44349181375

U2 - 10.1016/j.tet.2008.04.068

DO - 10.1016/j.tet.2008.04.068

M3 - Article

SN - 0040-4020

VL - 64

SP - 6482

EP - 6487

JO - Tetrahedron

JF - Tetrahedron

IS - 27

ER -

Exploiting the Anders-Gaßner variant on the Wittig reaction: new methodology for the synthesis of 3,3-dimethylacroyl enol esters

Abstract

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