Extreme ultraviolet laser excitation of isotopic molecular nitrogen: The dipole-allowed spectrum of 15N2 and 14N15N

J. P. Sprengers*, W. Ubachs, K. G.H. Baldwin, B. R. Lewis, W. U.L. Tchang-Brillet

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    48 Citations (Scopus)

    Abstract

    An XUV-laser-spectroscopic study of the 1Πu and 1Σu+ states of the isotopomers 15N2 and 14N15N was performed. new data on 26 absorption bands were obtained with the highest resolving power and precision achievable using present-day XUV-laser technology. New molecular spectroscopic parameters and precise isotope shifts were determined, which will help to inform future models of the molecular structure, interactions, and dynamics of N2.

    Original languageEnglish
    Pages (from-to)3160-3173
    Number of pages14
    JournalJournal of Chemical Physics
    Volume119
    Issue number6
    DOIs
    Publication statusPublished - 8 Aug 2003

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