Five-coordinate hydrido-ruthenium(II) complexes featuring n-heterocyclic silylene and carbene ligands

Ian A. Cade; Anthony F. Hill; Alexander Kämpfe; Jörg Wagler

doi:10.1021/om100146m

Five-coordinate hydrido-ruthenium(II) complexes featuring n-heterocyclic silylene and carbene ligands

Ian A. Cade, Anthony F. Hill, Alexander Kämpfe, Jörg Wagler

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

The reactions of [RuCl₂(=CHPh)(PCy₃)₂] or [RuHCl(=-H₂)(PCy₃)₂] with the N-heterocyclic silylene:Si(N^tBuCH)₂ (ISi^tBu) affords the coordinatively unsaturated silylene complex [RuHCl(ISi^tBu)(PCy ₃)₂]. For comparative purposes, the corresponding complex [RuHCl(IⁱPr)(PCy₃)₂] (IⁱPr =:C(NⁱPrCH)₂) was obtained from [RuHCl(ν-H ₂)(PCy₃)₂] and IⁱPr.

Original language	English
Pages (from-to)	4012-4017
Number of pages	6
Journal	Organometallics
Volume	29
Issue number	18
DOIs	https://doi.org/10.1021/om100146m
Publication status	Published - 27 Sept 2010

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@article{715935c532eb4d20ad8c5ea24fbefb9a,

title = "Five-coordinate hydrido-ruthenium(II) complexes featuring n-heterocyclic silylene and carbene ligands",

abstract = "The reactions of [RuCl2(=CHPh)(PCy3)2] or [RuHCl(=-H2)(PCy3)2] with the N-heterocyclic silylene:Si(NtBuCH)2 (ISitBu) affords the coordinatively unsaturated silylene complex [RuHCl(ISitBu)(PCy 3)2]. For comparative purposes, the corresponding complex [RuHCl(IiPr)(PCy3)2] (IiPr =:C(NiPrCH)2) was obtained from [RuHCl(ν-H 2)(PCy3)2] and IiPr.",

author = "Cade, {Ian A.} and Hill, {Anthony F.} and Alexander K{\"a}mpfe and J{\"o}rg Wagler",

year = "2010",

month = sep,

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doi = "10.1021/om100146m",

language = "English",

volume = "29",

pages = "4012--4017",

journal = "Organometallics",

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T1 - Five-coordinate hydrido-ruthenium(II) complexes featuring n-heterocyclic silylene and carbene ligands

AU - Cade, Ian A.

AU - Hill, Anthony F.

AU - Kämpfe, Alexander

AU - Wagler, Jörg

PY - 2010/9/27

Y1 - 2010/9/27

N2 - The reactions of [RuCl2(=CHPh)(PCy3)2] or [RuHCl(=-H2)(PCy3)2] with the N-heterocyclic silylene:Si(NtBuCH)2 (ISitBu) affords the coordinatively unsaturated silylene complex [RuHCl(ISitBu)(PCy 3)2]. For comparative purposes, the corresponding complex [RuHCl(IiPr)(PCy3)2] (IiPr =:C(NiPrCH)2) was obtained from [RuHCl(ν-H 2)(PCy3)2] and IiPr.

AB - The reactions of [RuCl2(=CHPh)(PCy3)2] or [RuHCl(=-H2)(PCy3)2] with the N-heterocyclic silylene:Si(NtBuCH)2 (ISitBu) affords the coordinatively unsaturated silylene complex [RuHCl(ISitBu)(PCy 3)2]. For comparative purposes, the corresponding complex [RuHCl(IiPr)(PCy3)2] (IiPr =:C(NiPrCH)2) was obtained from [RuHCl(ν-H 2)(PCy3)2] and IiPr.

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U2 - 10.1021/om100146m

DO - 10.1021/om100146m

M3 - Article

SN - 0276-7333

VL - 29

SP - 4012

EP - 4017

JO - Organometallics

JF - Organometallics

IS - 18

ER -

Five-coordinate hydrido-ruthenium(II) complexes featuring n-heterocyclic silylene and carbene ligands

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