Formation of ethane from mono-methyl palladium(II) complexes

Monica D. Lotz; Matthew S. Remy; David B. Lao; Alireza Ariafard; Brian F. Yates; Allan J. Canty; James M. Mayer; Melanie S. Sanford

doi:10.1021/ja412338k

Formation of ethane from mono-methyl palladium(II) complexes

Monica D. Lotz, Matthew S. Remy, David B. Lao, Alireza Ariafard, Brian F. Yates, Allan J. Canty^*, James M. Mayer, Melanie S. Sanford

^*Corresponding author for this work

Research School of Chemistry

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

This article describes the high-yielding and selective oxidatively induced formation of ethane from mono-methyl palladium complexes. Mechanistic details of this reaction have been explored via both experiment and computation. On the basis of these studies, a mechanism involving methyl group transmetalation between Pd^II and Pd^IV interediates is proposed.

Original language	English
Pages (from-to)	8237-8242
Number of pages	6
Journal	Journal of the American Chemical Society
Volume	136
Issue number	23
DOIs	https://doi.org/10.1021/ja412338k
Publication status	Published - 11 Jun 2014

Access to Document

10.1021/ja412338k

Cite this

@article{49dd98210b0746f0ab2b6ad55bda30e0,

title = "Formation of ethane from mono-methyl palladium(II) complexes",

abstract = "This article describes the high-yielding and selective oxidatively induced formation of ethane from mono-methyl palladium complexes. Mechanistic details of this reaction have been explored via both experiment and computation. On the basis of these studies, a mechanism involving methyl group transmetalation between PdII and PdIV interediates is proposed.",

author = "Lotz, {Monica D.} and Remy, {Matthew S.} and Lao, {David B.} and Alireza Ariafard and Yates, {Brian F.} and Canty, {Allan J.} and Mayer, {James M.} and Sanford, {Melanie S.}",

year = "2014",

month = jun,

day = "11",

doi = "10.1021/ja412338k",

language = "English",

volume = "136",

pages = "8237--8242",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "23",

}

TY - JOUR

T1 - Formation of ethane from mono-methyl palladium(II) complexes

AU - Lotz, Monica D.

AU - Remy, Matthew S.

AU - Lao, David B.

AU - Ariafard, Alireza

AU - Yates, Brian F.

AU - Canty, Allan J.

AU - Mayer, James M.

AU - Sanford, Melanie S.

PY - 2014/6/11

Y1 - 2014/6/11

N2 - This article describes the high-yielding and selective oxidatively induced formation of ethane from mono-methyl palladium complexes. Mechanistic details of this reaction have been explored via both experiment and computation. On the basis of these studies, a mechanism involving methyl group transmetalation between PdII and PdIV interediates is proposed.

AB - This article describes the high-yielding and selective oxidatively induced formation of ethane from mono-methyl palladium complexes. Mechanistic details of this reaction have been explored via both experiment and computation. On the basis of these studies, a mechanism involving methyl group transmetalation between PdII and PdIV interediates is proposed.

UR - http://www.scopus.com/inward/record.url?scp=84902281218&partnerID=8YFLogxK

U2 - 10.1021/ja412338k

DO - 10.1021/ja412338k

M3 - Article

AN - SCOPUS:84902281218

SN - 0002-7863

VL - 136

SP - 8237

EP - 8242

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 23

ER -

Formation of ethane from mono-methyl palladium(II) complexes

Abstract

Access to Document

Other files and links

Fingerprint

Cite this