Formation of ethane from mono-methyl palladium(II) complexes

Monica D. Lotz; Matthew S. Remy; David B. Lao; Alireza Ariafard; Brian F. Yates; Allan J. Canty; James M. Mayer; Melanie S. Sanford

doi:10.1021/ja412338k

Formation of ethane from mono-methyl palladium(II) complexes

Monica D. Lotz, Matthew S. Remy, David B. Lao, Alireza Ariafard, Brian F. Yates, Allan J. Canty^*, James M. Mayer, Melanie S. Sanford

^*Corresponding author for this work

Research School of Chemistry

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

This article describes the high-yielding and selective oxidatively induced formation of ethane from mono-methyl palladium complexes. Mechanistic details of this reaction have been explored via both experiment and computation. On the basis of these studies, a mechanism involving methyl group transmetalation between Pd^II and Pd^IV interediates is proposed.

Original language	English
Pages (from-to)	8237-8242
Number of pages	6
Journal	Journal of the American Chemical Society
Volume	136
Issue number	23
DOIs	https://doi.org/10.1021/ja412338k
Publication status	Published - 11 Jun 2014

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title = "Formation of ethane from mono-methyl palladium(II) complexes",

abstract = "This article describes the high-yielding and selective oxidatively induced formation of ethane from mono-methyl palladium complexes. Mechanistic details of this reaction have been explored via both experiment and computation. On the basis of these studies, a mechanism involving methyl group transmetalation between PdII and PdIV interediates is proposed.",

author = "Lotz, \{Monica D.\} and Remy, \{Matthew S.\} and Lao, \{David B.\} and Alireza Ariafard and Yates, \{Brian F.\} and Canty, \{Allan J.\} and Mayer, \{James M.\} and Sanford, \{Melanie S.\}",

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AU - Lotz, Monica D.

AU - Remy, Matthew S.

AU - Lao, David B.

AU - Ariafard, Alireza

AU - Yates, Brian F.

AU - Canty, Allan J.

AU - Mayer, James M.

AU - Sanford, Melanie S.

PY - 2014/6/11

Y1 - 2014/6/11

N2 - This article describes the high-yielding and selective oxidatively induced formation of ethane from mono-methyl palladium complexes. Mechanistic details of this reaction have been explored via both experiment and computation. On the basis of these studies, a mechanism involving methyl group transmetalation between PdII and PdIV interediates is proposed.

AB - This article describes the high-yielding and selective oxidatively induced formation of ethane from mono-methyl palladium complexes. Mechanistic details of this reaction have been explored via both experiment and computation. On the basis of these studies, a mechanism involving methyl group transmetalation between PdII and PdIV interediates is proposed.

UR - https://www.scopus.com/pages/publications/84902281218

U2 - 10.1021/ja412338k

DO - 10.1021/ja412338k

M3 - Article

AN - SCOPUS:84902281218

SN - 0002-7863

VL - 136

SP - 8237

EP - 8242

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 23

ER -

Formation of ethane from mono-methyl palladium(II) complexes

Abstract

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